[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation. (Q36143079)

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5 February 2020

title

[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation (English)

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3

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Ricardo García-Serres

6

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Wonwoo Nam

12

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author name string

Samuel A Wilson

1

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Junying Chen

2

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Yong-Min Lee

4

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Martin Clémancey

5

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Takashi Nomura

7

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Takashi Ogura

8

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Jean-Marc Latour

9

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Britt Hedman

10

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Keith O Hodgson

11

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Edward I Solomon

13

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language of work or name

English

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publication date

6 July 2012

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Journal of the American Chemical Society

5 February 2020

published in

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volume

134

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issue

28

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page(s)

11791-11806

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Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity

5 February 2020

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2 October 2017

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Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase

2 October 2017

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Spectroscopic and electronic structure studies of aromatic electrophilic attack and hydrogen-atom abstraction by non-heme iron enzymes

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2 October 2017

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New example of a non-heme mononuclear iron(IV) oxo complex. Spectroscopic data and oxidation activity

2 October 2017

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Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates

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An FeIV=O complex of a tetradentate tripodal nonheme ligand

2 October 2017

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Geometric and electronic structure/function correlations in non-heme iron enzymes

2 October 2017

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2 July 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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23 September 2018

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EXAFS spectroscopic evidence for an Fe=O unit in the Fe(IV) intermediate observed during oxygen activation by taurine:alpha-ketoglutarate dioxygenase

23 September 2018

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23 September 2018

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Direct detection of oxygen intermediates in the non-heme Fe enzyme taurine/alpha-ketoglutarate dioxygenase.

23 September 2018

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Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature.

23 September 2018

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Evidence for hydrogen abstraction from C1 of taurine by the high-spin Fe(IV) intermediate detected during oxygen activation by taurine:alpha-ketoglutarate dioxygenase (TauD).

23 September 2018

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The first direct characterization of a high-valent iron intermediate in the reaction of an alpha-ketoglutarate-dependent dioxygenase: a high-spin FeIV complex in taurine/alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli

23 September 2018

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Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations

23 September 2018

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Two interconverting Fe(IV) intermediates in aliphatic chlorination by the halogenase CytC3

21 October 2018

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Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

5 December 2018

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Formation of an aqueous oxoiron(IV) complex at pH 2-6 from a nonheme iron(II) complex and H2O2

5 December 2018

1 reference

12 December 2020

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

1 reference

12 December 2020

Aqueous FeIV==O: spectroscopic identification and oxo-group exchange

1 reference

12 December 2020

Ligand topology effect on the reactivity of a mononuclear nonheme iron(IV)-oxo complex in oxygenation reactions

1 reference

12 December 2020

A High-Spin Iron(IV)–Oxo Complex Supported by a Trigonal Nonheme Pyrrolide Platform

1 reference

12 December 2020

Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy

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12 December 2020

A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450

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12 December 2020

Visualization of solvation structures in liquid mixtures

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12 December 2020

Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+in Water/Acetone Mixtures‡

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA3046298

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22708532%20AND%20SRC:MED&resulttype=core&format=json

5 February 2020

1 reference

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5 February 2020

PubMed publication ID

22708532

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22708532%20AND%20SRC:MED&resulttype=core&format=json