Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions (Q29012891)

Europe PubMed Central

title

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions (English)

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23 March 2017

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2

Melanie S. Sanford

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23 March 2017

author name string

Thomas W. Lyons

series ordinal

1

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23 March 2017

publication date

10 February 2010

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23 March 2017

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23 March 2017

volume

110

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23 March 2017

issue

2

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23 March 2017

page(s)

1147-1169

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Modern Synthetic Methods for Copper-Mediated C(aryl)–O, C(aryl)–N, and C(aryl)–S Bond Formation

23 March 2017

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3 June 2018

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Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

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3 June 2018

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3 June 2018

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3 June 2018

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Carbon-heteroatom bond formation catalysed by organometallic complexes

3 June 2018

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Insights into directing group ability in palladium-catalyzed C-H bond functionalization

3 June 2018

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Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation.

3 June 2018

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Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides

3 June 2018

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Exclusive 5-exo-dig hydroarylation of o-alkynyl biaryls proceeding via C-H activation pathway

3 June 2018

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C-C, C-O, C-N bond formation on sp2 carbon by Pd(II)-catalyzed reactions involving oxidant agents

3 June 2018

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Reactions of hypervalent iodine reagents with palladium: mechanisms and applications in organic synthesis

3 June 2018

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Sigma-chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts: regioselectivity, stereoselectivity and catalytic turnover

3 June 2018

1 reference

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Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

3 June 2018

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Selected patented cross-coupling reaction technologies

3 June 2018

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The potential of palladacycles: more than just precatalysts.

3 June 2018

1 reference

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Understanding and exploiting C-H bond activation

3 June 2018

1 reference

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Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation.

3 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Mechanism of benzoquinone-promoted palladium-catalyzed oxidative cross-coupling reactions.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalyzed direct arylation of cyclic enamides with aryl silanes by sp(2) C-H activation.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Binuclear intermediates in oxidation reactions: [(Me(3)SiC[triple bond]C)Me(2)(bipy)Pt-PtMe(2)(bipy)](+) in the oxidation of Pt(II)Me(2)(bipy) (bipy = 2,2'-bipyridine) by IPh(C[triple bond]CSiMe(3))(OTf) (OTf = triflate).

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalysed direct synthesis of benzo[b]thiophenes from thioenols

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Synthesis of 1,2- and 1,3-dicarboxylic acids via Pd(II)-catalyzed carboxylation of aryl and vinyl C-H bonds

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Carbon-hydrogen bond functionalization approach for the synthesis of fluorenones and ortho-arylated benzonitriles

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Catalytic aerobic oxidation of substituted 8-methylquinolines in Pd(II)-2,6-pyridinedicarboxylic acid systems

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Synthesis of indolines and tetrahydroisoquinolines from arylethylamines by Pd(II)-catalyzed C-H activation reactions

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Direct ortho-acetoxylation of anilides via palladium-catalyzed sp(2) C-H bond oxidative activation

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalyzed oxidative ethoxycarbonylation of aromatic C-H bond with diethyl azodicarboxylate

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalyzed methylation of aryl C-H bond by using peroxides

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H Substrates

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Two methods for direct ortho-arylation of benzoic acids.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Indirect ortho functionalization of substituted toluenes through ortho olefination of N,N-dimethylbenzylamines tuned by the acidity of reaction conditions.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Ortho arylation of acetanilides via Pd(II)-catalyzed C-H functionalization.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Organometallic chemistry: C-H activation.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Intermolecular Amidation of Unactivated sp2and sp3C−H Bonds via Palladium-Catalyzed Cascade C−H Activation/Nitrene Insertion

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Highly selective C-H functionalization/halogenation of acetanilide.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

A Simple Catalytic Method for the Regioselective Halogenation of Arenes

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalyzed alkylation of aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Highly regioselective arylation of sp3 C-H bonds catalyzed by palladium acetate

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Regioselectivity in Palladium-Catalyzed C−H Activation/Oxygenation Reactions

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Preparation of benzolactams by Pd(OAc)2-catalyzed direct aromatic carbonylation.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

A highly selective catalytic method for the oxidative functionalization of C-H bonds

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Selective Pd-catalyzed oxidative coupling of anilides with olefins through C-H bond activation at room temperature

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Selective functionalization of amino acids in water: a synthetic method via catalytic C-H bond activation

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Catalytic Shilov chemistry: platinum chloride-catalyzed oxidation of terminal methyl groups by dioxygen.

26 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2836499

Activation of C−H Bonds by Metal Complexes

26 November 2018

1 reference

12 December 2020

Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects

1 reference

12 December 2020

Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

1 reference

12 December 2020

Aerobic oxidation of thiols to disulfides catalyzed by trichlorooxyvanadium

1 reference

12 December 2020

Palladium-catalyzed asymmetric iodination of unactivated C-H bonds under mild conditions

1 reference

12 December 2020

Catalytic coupling of haloolefins with anilides

1 reference

12 December 2020

Anilide ortho-arylation by using C-H activation methodology

1 reference

12 December 2020

Catalytic coupling of C-H and C-I bonds using pyridine as a directing group

1 reference

12 December 2020

Combined C-H functionalization/C-N bond formation route to carbazoles

1 reference

12 December 2020

Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation

1 reference

12 December 2020

C-H bond functionalization in complex organic synthesis

1 reference

12 December 2020

Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidant

1 reference

12 December 2020

Palladium-Catalyzed Oxidation ofBoc-ProtectedN-Methylamines with IOAc as the Oxidant: ABoc-Directed sp3C−H Bond Activation

1 reference

12 December 2020

Novel acetoxylation and C-C coupling reactions at unactivated positions in alpha-amino acid derivatives

1 reference

12 December 2020

Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways

1 reference

12 December 2020

Palladium-Catalyzed Methylation and Arylation of sp2and sp3C−H Bonds in Simple Carboxylic Acids

1 reference

12 December 2020

Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group

1 reference

12 December 2020

Palladium-catalyzed C-H activation/intramolecular amination reaction: a new route to 3-aryl/alkylindazoles

1 reference

12 December 2020

Multiple C-H activations to construct biologically active molecules in a process completely free of organohalogen and organometallic components

1 reference

12 December 2020

Pd(II)-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands

1 reference

12 December 2020

Pd(II)-catalyzed monoselective ortho halogenation of C-H bonds assisted by counter cations: a complementary method to directed ortho lithiation

1 reference

12 December 2020

Carbon-fluorine reductive elimination from a high-valent palladium fluoride

1 reference

12 December 2020

Palladium-catalyzed synthesis of 2-substituted benzothiazoles via a C-H functionalization/intramolecular C-S bond formation process

1 reference

12 December 2020

Synthesis of fluorenones from aromatic aldoxime ethers and aryl halides by palladium-catalyzed dual C-H activation and Heck cyclization

1 reference

12 December 2020

Palladium-catalyzed C-H bond functionalization with arylsulfonyl chlorides

1 reference

12 December 2020

Construction of nitrogen-containing heterocycles by C-H bond functionalization

1 reference

12 December 2020

Heterocycle formation via palladium-catalyzed intramolecular oxidative C-H bond functionalization: an efficient strategy for the synthesis of 2-aminobenzothiazoles

1 reference

12 December 2020

Palladium-catalyzed acylation of sp2 C-H bond: direct access to ketones from aldehydes

1 reference

12 December 2020

Palladium-catalyzed direct alkynylation of C-H bonds in benzenes

1 reference

12 December 2020

Palladium-catalyzed decarboxylative arylation of C-H bonds by aryl acylperoxides

1 reference

12 December 2020

Palladium(II)-catalyzed regioselective direct C2 alkenylation of indoles and pyrroles assisted by the N-(2-pyridyl)sulfonyl protecting group

1 reference

12 December 2020

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

1 reference

12 December 2020

Transition Metal Catalyzed Coupling Reactions under C-H Activation

1 reference

12 December 2020

Identifiers

DOI

10.1021/CR900184E

2 references

23 March 2017

1 reference

1 reference

PubMed publication ID

20078038

1 reference