Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion (Q29308505)

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:18216847%20AND%20SRC:MED&resulttype=core&format=json

1 January 2020

review article

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title

Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion (English)

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2

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1 January 2020

author name string

Huw M L Davies

series ordinal

1

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language of work or name

English

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publication date

1 January 2008

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1 January 2020

2 references

9 April 2017

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1 January 2020

volume

451

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issue

7177

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page(s)

417-424

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Navigating chemical space for biology and medicine

1 January 2020

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Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights

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Catalytic asymmetric reactions for organic synthesis: the combined C-H activation/Cope rearrangement

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Enantioselective carbon-hydrogen insertion is an effective and efficient methodology for the synthesis of (R)-(-)-baclofen

3 June 2018

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Synthesis of epothilones A and B in solid and solution phase

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Synthesis and pharmacology of potential cocaine antagonists. 2. Structure-activity relationship studies of aromatic ring-substituted methylphenidate analogs

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Organometallic chemistry: C-H activation.

3 June 2018

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A synthesis of (+)-saxitoxin

26 November 2018

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Combined C-H activation/cope rearrangement as a strategic reaction in organic synthesis: total synthesis of (-)-colombiasin a and (-)-elisapterosin B.

26 November 2018

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C-H activation as a strategic reaction: enantioselective synthesis of 4-substituted indoles

26 November 2018

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N-tosyloxycarbamates as a source of metal nitrenes: rhodium-catalyzed C-H insertion and aziridination reactions

26 November 2018

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Efficient total syntheses of (-)-colombiasin A and (-)-elisapterosin B: application of the Cr-catalyzed asymmetric quinone Diels-Alder reaction

26 November 2018

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Direct synthesis of (+)-erogorgiaene through a kinetic enantiodifferentiating step

26 November 2018

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Expanding the scope of C-H amination through catalyst design

26 November 2018

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Enantioselective total synthesis of erogorgiaene: applications of asymmetric Cu-catalyzed conjugate additions of alkylzincs to acyclic enones

26 November 2018

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A General Strategy to Elisabethane Diterpenes: Stereocontrolled Synthesis of Elisapterosin B via Oxidative Cyclization of an Elisabethin Precursor

26 November 2018

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Enantioselective indole Friedel--Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes

26 November 2018

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Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

26 November 2018

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New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to oxygen as a surrogate to the aldol reaction

26 November 2018

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New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to nitrogen as a surrogate for the mannich reaction

26 November 2018

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Unified strategy for the synthesis of (-)-elisapterosin B and (-)-colombiasin A.

26 November 2018

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Enantioselective synthesis of the bromopyrrole alkaloids manzacidin A and C by stereospecific C-h bond oxidation

26 November 2018

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Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis

26 November 2018

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Catalytic asymmetric C-H activation of silyl enol ethers as an equivalent of an asymmetric Michael reaction

26 November 2018

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A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones We thank Professors Brauman, Stack, Trost, and Wender for many helpful discussions. C.G.E. is the recipient of an NSF Predoctoral Fellowship. J.D.B. g

26 November 2018

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Catalytic asymmetric synthesis of diarylacetate and 4,4-diarylbutanoates. A formal asymmetric synthesis of (+)-sertraline

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12 December 2020

Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process

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Asymmetric catalytic C-H activation applied to the synthesis of syn-aldol products

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Total Synthesis of Colombiasin A This work was financially supported by the National Institutes of Health (USA) and The Skaggs Institute for Chemical Biology, postdoctoral fellowships from Bayer AG (to R.K. and W.M.), and grants from Abbott, Amgen,

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Rh(II)-Catalyzed Reaction Of Some alpha',alpha'- and beta'-Branched-O-Alkyl alpha-(Alkoxycarbonyl)-alpha-diazoacetates

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Catalytic asymmetric allylic C-H activation as a surrogate of the asymmetric Claisen rearrangement

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Recent Advances in Asymmetric Catalytic Metal Carbene Transformations

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Activation of C−H Bonds by Metal Complexes

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Optically active aromatic and heteroaromatic alpha-amino acids by a one-pot catalytic enantioselective addition of aromatic and heteroaromatic C-H bonds to alpha-imino esters

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Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

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Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds

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Double C-H activation strategy for the asymmetric synthesis of C2-symmetric anilines

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Highly Diastereoselective and Enantioselective C−H Functionalization of 1,2-Dihydronaphthalenes: A Combined C−H Activation/Cope Rearrangement Followed by a Retro-Cope Rearrangement

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Total synthesis of (-)-colombiasin A and (-)-elisapterosin B

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Recent Advances in Catalytic Intramolecular CH Aminations

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Enantioselective double C-H activation of dihydronaphthalenes

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C-H bond functionalization in complex organic synthesis

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A catalytic knight's move

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Efficient diastereoselective intermolecular rhodium-catalyzed C-H amination

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Enantioselective synthesis of β-amino esters and its application to the synthesis of the enantiomers of the antidepressant Venlafaxine

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Recent Advances in Catalytic Enantioselective Intermolecular CH Functionalization

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Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations

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De novo synthesis of Troc-protected amines: intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates

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Catalytic enantioselective synthesis of beta3-amino acids

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Palladium-Catalyzed Cross-Coupling Reactions in the Synthesis of Pharmaceuticals

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Identifiers

DOI

10.1038/NATURE06485

3 references

9 April 2017

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Dimensions Publication ID

1 January 2020

1035666678

0 references

1 reference

2 references

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1 January 2020

2 references