Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species (Q33936596)

30 July 2017

title

Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species (English)

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30 July 2017

Xiaopeng Shan

1

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30 July 2017

Lawrence Que

series ordinal

2

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30 July 2017

language of work or name

English

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publication date

31 March 2005

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Proceedings of the National Academy of Sciences of the United States of America

30 July 2017

published in

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30 July 2017

volume

102

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30 July 2017

issue

15

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30 July 2017

page(s)

5340-5345

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Synthetic models for non-heme carboxylate-bridged diiron metalloproteins: strategies and tactics.

30 July 2017

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Reactivity of hydroperoxide bound to a mononuclear non-heme iron site

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Heme-Containing Oxygenases

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Role of the nonheme Fe(II) center in the biosynthesis of the plant hormone ethylene

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Dioxygen binds end-on to mononuclear copper in a precatalytic enzyme complex

5 July 2018

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beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes

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Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization

21 January 2018

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A mechanistic study of the reaction between a diiron(II) complex [FeII(2)(mu-OH)2(6-Me3-TPA)2](2+) and O2 to form a diiron(III) peroxo complex

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End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry

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21 January 2018

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One-electron oxidation of a hydrogen-bonded phenol occurs by concerted proton-coupled electron transfer

21 January 2018

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Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity

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Combined Spectroscopic and Theoretical Evidence for a Persistent End-On Copper Superoxo Complex

29 October 2018

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The Ferroxidase Reaction of Ferritin Reveals a Diferric μ-1,2 Bridging Peroxide Intermediate in Common with Other O2-Activating Non-Heme Diiron Proteins†

21 January 2018

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Mechanistic Studies of the Formation and Decay of Diiron(III) Peroxo Complexes in the Reaction of Diiron(II) Precursors with Dioxygen

21 January 2018

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Peroxodiferric intermediate of stearoyl-acyl carrier protein delta 9 desaturase: oxidase reactivity during single turnover and implications for the mechanism of desaturation

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O2 activation by non-heme diiron proteins: identification of a symmetric mu-1,2-peroxide in a mutant of ribonucleotide reductase

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12 December 2020

Model for the cofactor formation reaction of E. coli ribonucleotide reductase. From a diiron(II) precursor to an FeIIIFeIV species via a peroxo intermediate

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Spectroscopic studies of isopenicillin N synthase. A mononuclear nonheme Fe2+ oxidase with metal coordination sites for small molecules and substrate

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Dioxygen binding to complexes with Fe(II)2(mu-OH)2 cores: steric control of activation barriers and O2-adduct formation

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12 December 2020

Heme/Copper Terminal Oxidases

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12 December 2020

[17O]Water and nitric oxide binding by protocatechuate 4,5-dioxygenase and catechol 2,3-dioxygenase. Evidence for binding of exogenous ligands to the active site Fe2+ of extradiol dioxygenases

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Reactions of Nitric Oxide with the Reduced Non-Heme Diiron Center of the Soluble Methane Monooxygenase Hydroxylase†

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A monomeric nickel-dioxygen adduct derived from a nickel(I) complex and O2

1 reference

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Identifiers

DOI

10.1073/PNAS.0409640102

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30 July 2017

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30 July 2017

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