A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity (Q35787888)

10 August 2017

title

A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity (English)

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10 August 2017

6

Edward I Solomon

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10 August 2017

Sunghee Kim

1

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10 August 2017

Jung Yoon Lee

2

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10 August 2017

Ryan E Cowley

3

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10 August 2017

Jake W Ginsbach

4

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10 August 2017

Maxime A Siegler

5

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10 August 2017

Kenneth D Karlin

7

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10 August 2017

language of work or name

English

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publication date

20 February 2015

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Journal of the American Chemical Society

10 August 2017

published in

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10 August 2017

volume

137

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10 August 2017

issue

8

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10 August 2017

page(s)

2796-2799

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Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex

10 August 2017

cites work

1 reference

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Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium

12 July 2018

1 reference

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Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity

12 July 2018

1 reference

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Reaction mechanism of the bicopper enzyme peptidylglycine α-hydroxylating monooxygenase

12 July 2018

1 reference

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Copper active sites in biology

12 July 2018

1 reference

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Cupric superoxo-mediated intermolecular C-H activation chemistry

12 July 2018

1 reference

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An anionic, tetragonal copper(II) superoxide complex

12 July 2018

1 reference

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Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species

12 July 2018

1 reference

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Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex

12 July 2018

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Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex

12 July 2018

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Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenases

12 July 2018

1 reference

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The copper-enzyme family of dopamine beta-monooxygenase and peptidylglycine alpha-hydroxylating monooxygenase: resolving the chemical pathway for substrate hydroxylation

12 July 2018

1 reference

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Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity

12 July 2018

1 reference

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Structure and spectroscopy of copper-dioxygen complexes.

12 July 2018

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Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent va

12 July 2018

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Nucleophilic reactivity of a copper(II)-superoxide complex.

12 July 2018

1 reference

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A copper complex supported by an N2S-tridentate ligand inducing efficient heterolytic O-O bond cleavage of alkylhydroperoxide.

25 September 2018

1 reference

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Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes

25 September 2018

1 reference

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Mononuclear copper(II)-superoxo complexes that mimic the structure and reactivity of the active centers of PHM and DbetaM.

25 September 2018

1 reference

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Imidazole substituent effects on oxidative reactivity of tripodal(imid)2(thioether)CuI complexes

25 September 2018

1 reference

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Catalytic mechanism of dopamine beta-monooxygenase mediated by Cu(III)-oxo.

25 September 2018

1 reference

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Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate

25 September 2018

1 reference

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Dioxygen binds end-on to mononuclear copper in a precatalytic enzyme complex

25 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4482613

Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site

25 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4482613

Hydroperoxo--copper(II) complex stabilized by N(S)s-type ligand having a phenyl thioether

25 September 2018

1 reference

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The Catalytic Mechanism of Peptidylglycine α-Hydroxylating Monooxygenase Investigated by Computer Simulation

25 September 2018

1 reference

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Copper versus thioether-centered oxidation: mechanistic insights into the non-innocent redox behavior of tripodal benzimidazolylaminothioether ligands

15 November 2018

1 reference

12 December 2020

A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols

1 reference

12 December 2020

Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation

1 reference

12 December 2020

Mechanisms Whereby Mononuclear Copper Proteins Functionalize Organic Substrates

1 reference

12 December 2020

Crystallographic characterization of a synthetic 1:1 end-on copper dioxygen adduct complex

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA511504N

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10 August 2017

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10 August 2017

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