Transition-metal-catalyzed synthesis of aspergillide B: an alkyne addition strategy (Q36125691)

12 August 2017

Transition-metal-catalyzed synthesis of aspergillide B: an alkyne addition strategy (English)

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12 August 2017

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ChEBI release 2020-05-28

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1

Barry M Trost

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12 August 2017

Mark J Bartlett

2

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PMCID

3407809

12 August 2017

language of work or name

English

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publication date

22 February 2012

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12 August 2017

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12 August 2017

14

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12 August 2017

5

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12 August 2017

1322-1325

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The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups

12 August 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Thionium ion initiated medium-sized ring formation: the total synthesis of asteriscunolide D

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Total synthesis of aspergillide A and B based on the transannular oxy-Michael reaction

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Synthesis and biological properties of the cytotoxic 14-membered macrolides aspergillide A and B.

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Enantioselective ProPhenol-catalyzed addition of 1,3-diynes to aldehydes to generate synthetically versatile building blocks and diyne natural products

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

3,3'-Anisyl-substituted BINOL, H(4)BINOL, and H(8)BINOL ligands: asymmetric synthesis of diverse propargylic alcohols and their ring-closing metathesis to chiral cycloalkenes

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Enantioselective formal total synthesis of (+)-aspergillide C.

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Highly enantioselective alkyne additions to aldehydes in the presence of 1,1'-bi-2-naphthol and hexamethylphosphoramide

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

The discovery of novel reactivity in the development of C-C bond-forming reactions: in situ generation of zinc acetylides with Zn(II)/R(3)N.

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Enantioselective synthesis of aspergillide B.

2 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Direct asymmetric Michael addition to nitroalkenes: vinylogous nucleophilicity under dinuclear zinc catalysis

23 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

New cytotoxic 14-membered macrolides from marine-derived fungus Aspergillus ostianus.

23 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Facile, mild, and highly enantioselective alkynylzinc addition to aromatic aldehydes by BINOL/N-methylimidazole dual catalysis.

23 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

A chemoselective reduction of alkynes to (E)-alkenes

23 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

A Unified Total Synthesis of Aspergillides A and B

23 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3407809

Routine use of natural abundance deuterium NMR in a polypeptidic chiral oriented solvent for the determination of the enantiomeric composition of chiral building blocks

5 December 2018

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12 December 2020

A Simple, Mild, Catalytic, Enantioselective Addition of Terminal Acetylenes to Aldehydes

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12 December 2020

Enantioselective total synthesis of aspergillide C

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12 December 2020

Efficient Enantioselective Additions of Terminal Alkynes and Aldehydes under Operationally Convenient Conditions

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12 December 2020

Asymmetric alkynylation of aldehydes with propiolates without high reagent loading and any additives

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12 December 2020

Concise total synthesis of (+)-aspergillide B

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12 December 2020

Efficient access to a dihydropyran-containing macrolide via a transannular oxy-Michael reaction: total synthesis of (+)-aspergillide C

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12 December 2020

Structure Revision of Aspergillides A and B, Cytotoxic 14-Membered Macrolides fromAspergillus ostianus, by X-ray Crystallography

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12 April 2024

https://opencitations.net/index/api/v1/citations/10.1246/CL.2009.384

Identifiers

DOI

10.1021/OL300200M

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12 August 2017

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12 August 2017

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PMCID

3407809