Enantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadiene (Q36226256)

12 August 2017

Enantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadiene (English)

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12 August 2017

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4

Michael J Krische

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12 August 2017

Jason R Zbieg

1

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12 August 2017

Eiji Yamaguchi

series ordinal

2

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12 August 2017

Emma L McInturff

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3

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12 August 2017

language of work or name

English

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publication date

22 March 2012

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12 August 2017

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12 August 2017

336

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12 August 2017

6079

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12 August 2017

324-327

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Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods

12 August 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation

1 October 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

A more comprehensive and highly practical solution to enantioselective aldehyde crotylation

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Iridium Catalyzed Hydro-hydroxyalkylation of Butadiene: Carbonyl Crotylation

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

anti-Diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level employing a cyclometallated iridium catalyst: alpha-methyl allyl acetate as a surrogate to preformed crotylmetal reagents

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Ruthenium-catalyzed C-C bond forming transfer hydrogenation: carbonyl allylation from the alcohol or aldehyde oxidation level employing acyclic 1,3-dienes as surrogates to preformed allyl metal reagents

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Critical assessment of pharmaceutical processes--A rationale for changing the synthetic route

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Enhanced anti-diastereo- and enantioselectivity in alcohol-mediated carbonyl crotylation using an isolable single component iridium catalyst

1 October 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Amplification of anti-diastereoselectivity via Curtin-Hammett effects in ruthenium-catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes: diastereoselective formation of all-carbon quaternary centers

29 June 2018

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction

29 June 2018

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Diastereo- and enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes: carbonyl syn-crotylation from the alcohol oxidation level

22 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

A powerful chiral counterion strategy for asymmetric transition metal catalysis

22 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones via rhodium-catalyzed asymmetric hydrogenation: mechanistic insight into the role of Brønsted acid additives.

22 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

22 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3439217

Rapid chromatographic technique for preparative separations with moderate resolution

22 September 2018

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Crossref

https://api.crossref.org/works/10.1126%2FSCIENCE.1219274

Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids

21 January 2018

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12 December 2020

Enantioselective hydrovinylation via asymmetric counteranion-directed ruthenium catalysis

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12 December 2020

Catalytic enantioselective allylation of carbonyl compounds and imines

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12 December 2020

Dual Catalysis: A Combined Enantioselective Brønsted Acid and Metal-Catalyzed Reaction—Metal Catalysis with Chiral Counterions

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12 December 2020

Chiral counteranions in asymmetric transition-metal catalysis: highly enantioselective Pd/Brønsted acid-catalyzed direct alpha-allylation of aldehydes

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12 December 2020

Asymmetric counteranion-directed transition-metal catalysis: enantioselective epoxidation of alkenes with manganese(III) salen phosphate complexes

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12 December 2020

Reduction of aldehydes and ketones by transfer hydrogenation with 1,4-butanediol

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12 December 2020

Chiral synthesis via organoboranes. 7. Diastereoselective and enantioselective synthesis of erythro- and threo-.beta.-methylhomoallyl alcohols via enantiomeric (Z)- and (E)-crotylboranes

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12 December 2020

Identifiers

DOI

10.1126/SCIENCE.1219274

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12 August 2017

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12 August 2017

PubMed publication ID

22442385

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