Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex (Q36901523)

17 August 2017

Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex (English)

1 reference

17 August 2017

William W. Brennessel

series ordinal

3

object named as

William W Brennessel

1 reference

17 August 2017

Azwana R Sadique

1

1 reference

17 August 2017

Elizabeth A Gregory

series ordinal

2

1 reference

17 August 2017

Patrick L Holland

series ordinal

4

1 reference

17 August 2017

language of work or name

English

0 references

publication date

12 June 2007

1 reference

Journal of the American Chemical Society

17 August 2017

1 reference

17 August 2017

129

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17 August 2017

26

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17 August 2017

8112-8121

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Connecting nitrogenase intermediates with the kinetic scheme for N2 reduction by a relaxation protocol and identification of the N2 binding state.

17 August 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+.

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Mid- to high-valent imido and nitrido complexes of iron

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Studies of low-coordinate iron dinitrogen complexes

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Trapping H- bound to the nitrogenase FeMo-cofactor active site during H2 evolution: characterization by ENDOR spectroscopy

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Substrate interactions with nitrogenase: Fe versus Mo.

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Speculative synthetic chemistry and the nitrogenase problem

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactor

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Mechanism of Molybdenum Nitrogenase

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Cleavage of nitrogen-hydrogen bonds of ammonia induced by triruthenium polyhydrido clusters.

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

[(C5Me5)2U][(mu-Ph)2BPh2] as a four electron reductant

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Heterolytic H2 activation mediated by low-coordinate L3Fe-(mu-N)-FeL3 complexes to generate Fe(mu-NH)(mu-H)Fe species

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Mössbauer, electron paramagnetic resonance, and crystallographic characterization of a high-spin Fe(I) diketiminate complex with orbital degeneracy

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Trapping a hydrazine reduction intermediate on the nitrogenase active site

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Substrate interactions with the nitrogenase active site

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Ground-state singlet L3Fe-(mu-N)-FeL3 and L3Fe(NR) complexes featuring pseudotetrahedral Fe(II) centers.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Substrate interaction at an iron-sulfur face of the FeMo-cofactor during nitrogenase catalysis

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (Fe(IV)N) and dinitrogen (Fe(I)-N2-Fe(I)) ligands

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Hydrogenolysis of [PhBP3]Fe[triple bond]N-p-tolyl: probing the reactivity of an iron imide with H2.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

N=N bond cleavage by a low-coordinate ironII hydride complex

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

A low-spin d5 iron imide: nitrene capture by low-coordinate iron(I) provides the 4-coordinate Fe(III) complex [PhB(CH2PPh2)3]Fe=N-p-tolyl

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Electrochemical cleavage of N=N bonds at a Mo2(mu-SMe)3 site relevant to the biological reduction of dinitrogen at a bimetallic sulfur centre

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Intermediates Trapped during Nitrogenase Reduction of N⋮N, CH3−NNH, and H2N−NH2

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2548314

Catalytic Reduction of Hydrazine to Ammonia with MoFe(3)S(4)-Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase

4 December 2018

1 reference

12 December 2020

Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(eta(2)-PhN=NPh)

1 reference

12 December 2020

Electrochemical Reduction of Nitrogenous Ligands at a Conserved Dinuclear Metal-Sulfur Site: Cleavage of the N=N Bond of Phenyldiazene and Reduction of an Imide to NH(3)

1 reference

12 December 2020

The Persistent Radical Effect: A Principle for Selective Radical Reactions and Living Radical Polymerizations

1 reference

12 December 2020

Structureminus signFunction Relationships of Alternative Nitrogenases

1 reference

12 December 2020

Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex

1 reference

12 December 2020

The hydrogen chemistry of the FeMo-co active site of nitrogenase

1 reference

12 December 2020

Synthesis and hydrogenation of bis(imino)pyridine iron imides

1 reference

12 December 2020

Mechanistic significance of the preparatory migration of hydrogen atoms around the FeMo-co active site of nitrogenase

1 reference

12 December 2020

Binding affinity of alkynes and alkenes to low-coordinate iron

1 reference

12 December 2020

Coordination-number dependence of reactivity in an imidoiron(III) complex

1 reference

12 December 2020

Coordination chemistry of H2 and N2 in aqueous solution. Reactivity and mechanistic studies using trans-FeII(P2)2X2)-type complexes (P2 = a chelating, water-solubilizing phosphine)

1 reference

12 December 2020

A Simple Preparative Route to Bis(imido)uranium(VI) Complexes by the Direct Reductions of Diazenes and Azides

1 reference

12 December 2020

Nitrogenase reactivity: insight into the nitrogen-fixing process through hydrogen-inhibition and HD-forming reactions

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA069199R

1 reference

17 August 2017

1 reference

17 August 2017

PubMed publication ID

17564444

1 reference