Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight (Q37218691)

19 August 2017

Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight (English)

1 reference

19 August 2017

3

Robert G Bergman

1 reference

19 August 2017

Jared C Lewis

1

1 reference

19 August 2017

Ashley M Berman

series ordinal

2

1 reference

19 August 2017

Jonathan A Ellman

series ordinal

4

1 reference

19 August 2017

language of work or name

English

0 references

publication date

2 February 2008

1 reference

Journal of the American Chemical Society

19 August 2017

1 reference

19 August 2017

130

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19 August 2017

8

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19 August 2017

2493-2500

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Copper-catalyzed arylation of heterocycle C-H bonds

19 August 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Palladium-catalyzed benzene arylation: incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Catalytic intermolecular direct arylation of perfluorobenzenes.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Analysis of the reactions used for the preparation of drug candidate molecules

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Palladium-catalyzed arylation and heteroarylation of indolizines

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Catalytic C-h/olefin coupling

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Synthetic Principles for Bandgap Control in Linear pi-Conjugated Systems

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Bidentate phosphorus baskets by intramolecular phosphinidene addition

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Annulation of aromatic imines via directed C-H bond activation

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Dibenzo[a,d]cycloheptenyl dibenzophosphole palladium dichloride: synthesis, X-ray-crystal structure and application in the Suzuki-Miyaura coupling

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Intermolecular coupling of alkenes to heterocycles via C-H bond activation

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Olefins as steering ligands for homogeneously catalyzed hydrogenations

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Synthesis of unprotected and borane-protected cyclic phosphines using Ru- and Mo- based olefin metathesis catalysts

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

A mechanistic alternative for the intramolecular hydroboration of homoallylic amine and phosphine borane complexes

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Facile synthesis of 2,5-diarylthiazoles via palladium-catalyzed tandem C-H substitutions. Design of tunable light emission and liquid crystalline characteristics

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Regioselective palladium-catalyzed arylation of 3-carboalkoxy furan and thiophene.

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Palladium-catalyzed multiple arylation of thiophenes.

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Novel Synthesis of Borane Complexes of Cyclic Phosphanes Using Ruthenium-Catalyzed Olefin Metathesis This work was supported by the European Community Training and Mobility Research Programme (COSSAC, ERBFMRXCT 980193 to M.S.) and by the Nuffield Fo

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

3 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2693036

Regioselective palladium-catalyzed arylation of 2-furaldehyde

4 December 2018

1 reference

12 December 2020

Anilide ortho-arylation by using C-H activation methodology

1 reference

12 December 2020

Palladium-catalyzed cross-coupling of pyrrole anions with aryl chlorides, bromides, and iodides

1 reference

12 December 2020

The catalytic cross-coupling of unactivated arenes

1 reference

12 December 2020

Palladium-catalyzed regioselective arylation of imidazo[1,2-a]pyrimidine

1 reference

12 December 2020

4-Aryl/cycloalkyl-5-phenyloxazole derivatives as selective COX-2 inhibitors

1 reference

12 December 2020

Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis

1 reference

12 December 2020

Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds

1 reference

12 December 2020

Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides

1 reference

12 December 2020

Thermal, Catalytic, Regiospecific Functionalization of Alkanes

1 reference

12 December 2020

Palladium-catalyzed arylation of electron-rich heterocycles with aryl chlorides

1 reference

12 December 2020

Chiral phosphane alkenes (PALs): simple synthesis, applications in catalysis, and functional hemilability

1 reference

12 December 2020

Direct arylation reactions catalyzed by Pd(OH)2/C: evidence for a soluble palladium catalyst

1 reference

12 December 2020

Metal-Mediated Reductive Hydrodehalogenation of Organic Halides

1 reference

12 December 2020

Substituted imidazoles as glucagon receptor antagonists

1 reference

12 December 2020

An investigation of imidazole and oxazole syntheses using aryl-substituted TosMIC reagents

1 reference

12 December 2020

Direct C-H arylation of purines: development of methodology and its use in regioselective synthesis of 2,6,8-trisubstituted purines

1 reference

12 December 2020

Mild and general conditions for the cross-coupling of aryl halides with pentafluorobenzene and other perfluoroaromatics

1 reference

12 December 2020

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization

1 reference

12 December 2020

Potent, orally absorbed glucagon receptor antagonists

1 reference

12 December 2020

Highly efficient monophosphine-based catalyst for the palladium-catalyzed suzuki-miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters

1 reference

12 December 2020

Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes

1 reference

12 December 2020

Air-stable trialkylphosphonium salts: simple, practical, and versatile replacements for air-sensitive trialkylphosphines. Applications in stoichiometric and catalytic processes

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA0748985

1 reference

19 August 2017

1 reference

19 August 2017

PubMed publication ID

18251465

1 reference