Enantioselective, organocatalytic Morita-Baylis-Hillman and Aza-Morita-Baylis-Hillman reactions: stereochemical issues. (Q37718530)

PubMed publication ID

22 August 2017

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title

Enantioselective, organocatalytic Morita-Baylis-Hillman and Aza-Morita-Baylis-Hillman reactions: stereochemical issues (English)

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

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1

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

author name string

José M Saá

series ordinal

2

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

language of work or name

English

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publication date

1 February 2010

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PubMed publication ID

22 August 2017

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

volume

15

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

issue

2

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

page(s)

709-734

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

Creative Commons Attribution 4.0 International

13 May 2020

copyright license

start time

1 February 2010

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April 2022 Public Data File from Crossref

copyright status

copyrighted

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cites work

aza-Baylis-Hillman reaction

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12 December 2020

In Search of Peptide-Based Catalysts for Asymmetric Organic Synthesis

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12 December 2020

N-heterocyclic carbene catalyzed aza-Morita-Baylis-Hillman reaction of cyclic enones with N-tosylarylimines

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12 December 2020

Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes

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12 December 2020

Mechanistic implications in the Morita-Baylis-Hillman alkylation: isolation and characterization of an intermediate

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12 December 2020

Chiral binaphthyl-derived amine-thiourea organocatalyst-promoted asymmetric Morita-Baylis-Hillman reaction

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12 December 2020

Bifunctional Organocatalysts for Enantioselective aza-Morita−Baylis−Hillman Reaction

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12 December 2020

New Strategies for the Development of an Asymmetric Version of the Baylis-Hillman Reaction This work was supported by the Fonds der Chemischen Industrie (Liebig-scholarship and funds for P. L.). P. L. thanks Prof. Dr. A. de Meijere for his support

1 reference

12 December 2020

Dramatic rate acceleration of the Baylis-Hillman reaction in homogeneous medium in the presence of water

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12 December 2020

The Direct Catalytic Asymmetric Cross-Aldol Reaction of Aldehydes

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12 December 2020

A new interpretation of the Baylis-Hillman mechanism

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12 December 2020

The Baylis-Hillman reaction: a novel source of attraction, opportunities, and challenges in synthetic chemistry.

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12 December 2020

Dual Catalyst Control in the Enantioselective Intramolecular Morita−Baylis−Hillman Reaction

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12 December 2020

The enantioselective Morita-Baylis-Hillman reaction and its aza counterpart

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12 December 2020

Chiral phosphine Lewis base catalyzed asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with methyl vinyl ketone and phenyl acrylate

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12 December 2020

Polymer-supported organic catalysts

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12 December 2020

Efficient Baylis--Hillman reaction using stoichiometric base catalyst and an aqueous medium

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12 December 2020

Asymmetric Morita-Baylis-Hillman reaction of arylaldehydes with 2-cyclohexen-1-one catalyzed by chiral bis(thio)urea and DABCO

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12 December 2020

Traditional Morita-Baylis-Hillman reaction of aldehydes with methyl vinyl ketone co-catalyzed by triphenylphosphine and nitrophenol

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12 December 2020

Trifunctional organocatalyst-promoted counterion catalysis for fast and enantioselective aza-Morita-Baylis-Hillman reactions at ambient temperature.

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12 December 2020

Dual Catalyst Control in the Amino Acid-Peptide-Catalyzed Enantioselective Baylis−Hillman Reaction

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12 December 2020

Computational evidence for the enamine mechanism of intramolecular aldol reactions catalyzed by proline

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12 December 2020

Enantioselective Organocatalysis

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12 December 2020

Asymmetric organocatalysis

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12 December 2020

Chiral phosphine lewis bases catalyzed asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with activated olefins

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12 December 2020

Direct Catalytic Asymmetric Enolexo Aldolizations

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12 December 2020

Recent Advances in the Baylis−Hillman Reaction and Applications

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12 December 2020

Diastereo- and enantioselective Aza-MBH-type reaction of nitroalkenes to N-tosylimines catalyzed by bifunctional organocatalysts

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12 December 2020

Quantum mechanical predictions of the stereoselectivities of proline-catalyzed asymmetric intermolecular aldol reactions

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12 December 2020

Intramolecular tandem Michael-type addition/aldol cyclization induced by TiCl(4)-R(4)NX combinations

1 reference

12 December 2020

Influence of Michael acceptor stereochemistry on intramolecular Morita-Baylis-Hillman reactions

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12 December 2020

Theoretical studies of stereoselectivities of intramolecular aldol cyclizations catalyzed by amino acids.

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12 December 2020

Magnitudes and chemical consequences of R(3)N(+)-C-H...O[double bond]C hydrogen bonding

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12 December 2020

Catalytic, asymmetric Baylis-Hillman reaction of imines with methyl vinyl ketone and methyl acrylate

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12 December 2020

Dualistic nature of the mechanism of the Morita-Baylis-Hillman reaction probed by electrospray ionization mass spectrometry.

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12 December 2020

beta-Isocupreidine-catalyzed asymmetric Baylis-Hillman reaction of imines

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12 December 2020

Lewis Base Catalysis in Organic Synthesis

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12 December 2020

Density functional study of proline-catalyzed intramolecular Baylis-Hillman reactions.

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12 December 2020

Intramolecular Baylis-Hillman and morita reactions using unsaturated thiol ester substrates containing enolizable aldehydes

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12 December 2020

Bifunctional Activation and Racemization in the Catalytic Asymmetric Aza-Baylis−Hillman Reaction

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12 December 2020

The aldol addition reaction: an old transformation at constant rebirth

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12 December 2020

Mechanism of the Morita-Baylis-Hillman reaction: a computational investigation

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12 December 2020

Titanium isopropoxide as efficient catalyst for the aza-Baylis-Hillman reaction. Selective formation of alpha-methylene-beta-amino acid derivatives.

1 reference

12 December 2020

Highly enantioselective aza Morita-Baylis-Hillman reaction catalyzed by bifunctional beta-isocupreidine derivatives.

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12 December 2020

Probing the mechanism of the Baylis-Hillman reaction by electrospray ionization mass and tandem mass spectrometry

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12 December 2020

A Way to Highly Enantiomerically Enriched aza-Morita–Baylis–Hillman–Type Products

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12 December 2020

Cupreines and cupreidines: an emerging class of bifunctional cinchona organocatalysts

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12 December 2020

Highly Enantioselective Aza-Baylis–Hillman Reaction in a Chiral Reaction Medium

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12 December 2020

Ab initio and density functional theory evidence on the rate-limiting step in the Morita-Baylis-Hillman reaction

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12 December 2020

Asymmetric Morita−Baylis−Hillman Reactions Catalyzed by Chiral Brønsted Acids

1 reference

12 December 2020

A novel selective aza-Morita-Baylis-Hillman (aza-MBH) domino reaction and aza-MBH reaction of N-sulfonated imines with acrolein catalyzed by a bifunctional phosphine organocatalyst

1 reference

12 December 2020

Reevaluation of the Mechanism of the Baylis-Hillman Reaction: Implications for Asymmetric Catalysis

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12 December 2020

Baylis-Hillman mechanism: a new interpretation in aprotic solvents

1 reference

12 December 2020

Invertible enantioselectivity in 6'-deoxy-6'-acylamino-beta-isocupreidine-catalyzed asymmetric aza-Morita-Baylis-Hillman reaction: key role of achiral additive

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12 December 2020

The Morita-Baylis-Hillman reaction: insights into asymmetry and reaction mechanisms by electrospray ionization mass spectrometry.

1 reference

12 December 2020

In the Golden Age of Organocatalysis

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12 December 2020

Recent extensions of the Morita-Baylis-Hillman reaction

1 reference

12 December 2020

Correlation between pK(a) and reactivity of quinuclidine-based catalysts in the Baylis-Hillman reaction: discovery of quinuclidine as optimum catalyst leading to substantial enhancement of scope

1 reference

12 December 2020

Lewis base activation of Lewis acids: catalytic enantioselective glycolate aldol reactions

1 reference

12 December 2020

Water catalysis in the Morita-Baylis-Hillman reaction: a mechanistic perspective

1 reference

12 December 2020

The proline-catalyzed direct asymmetric three-component Mannich reaction: scope, optimization, and application to the highly enantioselective synthesis of 1,2-amino alcohols

1 reference

12 December 2020

10.3390/MOLECULES15020709

Identifiers

DOI

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=PMCID:PMC6263197&resulttype=core&format=json

13 May 2020

PubMed publication ID

20335941

1 reference