Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (-)-Clavosolide A. (Q38497852)

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scientific article published on 14 January 2016

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English	Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (-)-Clavosolide A.	scientific article published on 14 January 2016

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scholarly article

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5 March 2020

Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (-)-Clavosolide A (English)

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5 March 2020

Varinder Aggarwal

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5 March 2020

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5 March 2020

Jack Li-Yang Chen

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5 March 2020

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James R Smith

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14 January 2016

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5 March 2020

Angewandte Chemie International Edition

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2498-2502

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5 March 2020

Total Synthesis of Clavosolide A via Tandem Allylic Oxidation/Oxa-Conjugate Addition Reaction

1 reference

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6 September 2017

Strategies for the construction of tetrahydropyran rings in the synthesis of natural products

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6 September 2017

Cyclopropane compatibility with oxidative carbocation formation: total synthesis of clavosolide A

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6 September 2017

Prins-type macrocyclizations as an efficient ring-closing strategy in natural product synthesis

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6 September 2017

Recent progress on the total synthesis of acetogenins from Annonaceae

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6 September 2017

Stereoselective cyclopropanation reactions

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6 September 2017

Highly diastereo- and enantioselective allylboration of aldehydes using α-substituted allyl/crotyl pinacol boronic esters via in situ generated borinic esters.

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23 June 2018

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23 June 2018

Enantioselective homocrotylboration of aliphatic aldehydes

1 reference

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23 June 2018

Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

1 reference

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31 August 2018

Synthesis of enantioenriched tertiary boronic esters by the lithiation/borylation of secondary alkyl benzoates

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31 August 2018

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols.

1 reference

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31 August 2018

Intramolecular Prins cyclisations for the stereoselective synthesis of bicyclic tetrahydropyrans

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4755224

31 August 2018

Total synthesis of the marine natural product (-)-clavosolide A.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4755224

31 August 2018

Total synthesis of the marine natural product (-)-clavosolide A. A showcase for the Petasis-Ferrier union/rearrangement tactic.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4755224

31 August 2018

An efficient and practical synthesis of beta-(1 --> 3)-linked xylooligosaccharides

1 reference

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31 August 2018

Novel tools for the study of class I alpha-mannosidases: a chromogenic substrate and a substrate-analog inhibitor

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31 August 2018

Clavosolides A and B, dimeric macrolides from the Philippines sponge Myriastra clavosa

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31 August 2018

Enantioselektive Synthese mit Lithium/(−)-Spartein-Carbanion-Paaren

1 reference

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21 January 2018

Recent developments in chemical oligosaccharide synthesis

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21 January 2018

Fast and selective oxidation of primary alcohols to aldehydes or to carboxylic acids and of secondary alcohols to ketones mediated by oxoammonium salts under two-phase conditions

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201511140

21 January 2018

Stereodivergent Total Synthesis of Δ9-Tetrahydrocannabinols

1 reference

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12 December 2020

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Lithiated carbamates: chiral carbenoids for iterative homologation of boranes and boronic esters

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https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

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Short stereoselective synthesis of the Phytophthora universal mating hormone α1 using lithiation/borylation reactions

1 reference

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12 December 2020

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An efficient formal synthesis of (-)-clavosolide a featuring a "mismatched" stereoselective oxocarbenium reduction

1 reference

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Stereoselective synthesis of 4-hydroxy-2,3,6-trisubstituted tetrahydropyrans

1 reference

https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

based on heuristic

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Enantioselective total synthesis of (-)-clavosolide B

1 reference

https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

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Investigation of functionalized α-chloroalkyllithiums for a stereospecific reagent-controlled homologation approach to the analgesic alkaloid (-)-epibatidine

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12 December 2020

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Iterative stereospecific reagent-controlled homologation of pinacol boronates by enantioenriched alpha-chloroalkyllithium reagents

1 reference

https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

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Cationic palladium(II)-catalyzed stereoselective glycosylation with glycosyl trichloroacetimidates

1 reference

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12 December 2020

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Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemist

1 reference

https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane

1 reference

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12 December 2020

based on heuristic

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Use of alkyl 2,4,6-triisopropylbenzoates in the asymmetric homologation of challenging boronic esters

1 reference

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12 December 2020

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Competitive Silyl-Prins Cyclization versus Tandem Sakurai-Prins Cyclization: An Interesting Substitution Effect

1 reference

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Multicomponent Prins Cyclization from Allylsilyl Alcohols Leading to Dioxaspirodecanes

1 reference

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1 reference

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12 December 2020

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Short Convergent Synthesis of the Mycolactone Core Through Lithiation-Borylation Homologations

1 reference

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1 reference

https://pubmed.ncbi.nlm.nih.gov/26766494

12 December 2020

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Identifiers

10.1002/ANIE.201511140

1 reference

Europe PubMed Central

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:26766494%20AND%20SRC:MED&resulttype=core&format=json

5 March 2020

PMC publication ID

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Europe PubMed Central

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5 March 2020

PubMed publication ID

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Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:26766494%20AND%20SRC:MED&resulttype=core&format=json

5 March 2020

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