Redox potential and C-H bond cleaving properties of a nonheme Fe(IV)=O complex in aqueous solution. (Q41156601)

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2 February 2020

title

Redox potential and C-H bond cleaving properties of a nonheme Fe(IV)=O complex in aqueous solution (English)

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2 February 2020

3

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2 February 2020

author name string

Dong Wang

series ordinal

1

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2 February 2020

Mo Zhang

series ordinal

2

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2 February 2020

Lawrence Que

series ordinal

4

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2 February 2020

language of work or name

English

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publication date

1 June 2010

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Journal of the American Chemical Society

2 February 2020

published in

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volume

132

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2 February 2020

issue

22

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2 February 2020

page(s)

7638-7644

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A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity

2 February 2020

cites work

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A two-state reactivity model explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme oxoiron(IV) complexes

27 September 2017

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Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate

27 September 2017

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The road to non-heme oxoferryls and beyond

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Non-heme Fe(IV)-oxo intermediates

27 September 2017

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Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase

27 September 2017

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electrochemical generation of a nonheme oxoiron(IV) complex

27 September 2017

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High-valent nonheme iron-oxo species in biomimetic oxidations

27 September 2017

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Hydrogen Atom Abstraction by Permanganate: Oxidations of Arylalkanes in Organic Solvents

27 September 2017

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Trends in substrate hydroxylation reactions by heme and nonheme iron(IV)-oxo oxidants give correlations between intrinsic properties of the oxidant with barrier height.

27 September 2017

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Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes

14 June 2018

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Direct comparison of the reactivity of model complexes for Compounds 0, I, and II in oxygenation, hydrogen-abstraction, and hydride-transfer processes

19 August 2018

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Oxidative reactivity difference among the metal oxo and metal hydroxo moieties: pH dependent hydrogen abstraction by a manganese(IV) complex having two hydroxide ligands

19 August 2018

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Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

19 August 2018

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Spectroscopic evidence for a high-spin Br-Fe(IV)-oxo intermediate in the alpha-ketoglutarate-dependent halogenase CytC3 from Streptomyces

19 August 2018

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EXAFS spectroscopic evidence for an Fe=O unit in the Fe(IV) intermediate observed during oxygen activation by taurine:alpha-ketoglutarate dioxygenase

19 August 2018

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Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature.

19 August 2018

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Oxidation of C-H bonds by [(bpy)2(py)RuIVO]2+ occurs by hydrogen atom abstraction

19 August 2018

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End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry

19 August 2018

1 reference

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Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations

19 August 2018

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Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

2 December 2018

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Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes

2 December 2018

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12 December 2020

Coordination and Redox Chemistry of Substituted-Polypyridyl Complexes of Ruthenium

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12 December 2020

Mechanistic studies on peroxide activation by a water-soluble iron(III)-porphyrin: implications for O-O bond activation in aqueous and nonaqueous solvents

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12 December 2020

Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes

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12 December 2020

Oxygen-atom transfer between mononuclear nonheme iron(IV)-oxo and iron(II) complexes

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12 December 2020

Theoretical investigation of C--H hydroxylation by (N4Py)Fe(IV)=O(2+): an oxidant more powerful than P450?

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12 December 2020

Understanding the selectivity of a moderate oxidation catalyst: hydrogen abstraction by a fully characterized, activated catalyst, the robust dihydroxo manganese(IV) complex of a bridged cyclam

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12 December 2020

Iron Chemistry of a Pentadentate Ligand That Generates a Metastable Fe(III)-OOH Intermediate

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12 December 2020

Identifiers

DOI

10.1021/JA909923W

1 reference

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2 February 2020

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2 February 2020

PubMed publication ID

20476758

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