Total synthesis of (-)-N-methylwelwitindolinone B isothiocyanate via a chlorinative oxabicycle ring-opening strategy. (Q42957221)

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25275668%20AND%20SRC:MED&resulttype=core&format=json

20 February 2020

title

Total synthesis of (-)-N-methylwelwitindolinone B isothiocyanate via a chlorinative oxabicycle ring-opening strategy (English)

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20 February 2020

1

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20 February 2020

author name string

Evan D Styduhar

series ordinal

2

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20 February 2020

Emma L Baker

series ordinal

3

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20 February 2020

Neil K Garg

series ordinal

4

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20 February 2020

language of work or name

English

0 references

publication date

10 October 2014

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Journal of the American Chemical Society

20 February 2020

published in

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20 February 2020

volume

136

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20 February 2020

issue

42

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20 February 2020

page(s)

14710-14713

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Enantiospecific total synthesis of N-methylwelwitindolinone D isonitrile.

20 February 2020

cites work

1 reference

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Studies toward welwitindolinones: formal syntheses of N-methylwelwitindolinone C isothiocyanate and related natural products

26 May 2018

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Formal syntheses of naturally occurring welwitindolinones

26 May 2018

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Synthesis of functionalized cyclohexenone core of welwitindolinones via rhodium-catalyzed [5 + 1] cycloaddition

26 May 2018

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Total synthesis of oxidized welwitindolinones and (-)-N-methylwelwitindolinone C isonitrile

26 May 2018

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A unified route to the welwitindolinone alkaloids: total syntheses of (-)-N-methylwelwitindolinone C isothiocyanate, (-)-N-methylwelwitindolinone C isonitrile, and (-)-3-hydroxy-N-methylwelwitindolinone C isothiocyanate

26 May 2018

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Total synthesis of (-)-N-methylwelwitindolinone C isothiocyanate

26 May 2018

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Directed oxidative cyclizations to C2- or C4-positions of indole: efficient construction of the bicyclo[4.3.1]decane core of welwitindolinones.

26 May 2018

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Total synthesis of N-methylwelwitindolinone D isonitrile

26 May 2018

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Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition

26 May 2018

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Approaches to N-methylwelwitindolinone C isothiocyanate: facile synthesis of the tetracyclic core

26 May 2018

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Synthesis of the bicyclic welwitindolinone core via an alkylation/cyclization cascade reaction

26 May 2018

1 reference

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Enantiospecific total synthesis of the hapalindoles, fischerindoles, and welwitindolinones via a redox economic approach

26 May 2018

1 reference

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Welwistatin support studies: expansion and limitation of aryllead(IV) coupling reactions

26 May 2018

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An approach to the total synthesis of welwistatin

26 May 2018

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Reductive cleavage of aryl O-carbamates to phenols by the Schwartz reagent. Expedient link to the directed ortho metalation strategy.

26 May 2018

1 reference

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Confirmation of the configuration of 10-isothiocyanato-4-cadinene diastereomers through synthesis.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Total syntheses of the elusive welwitindolinones with bicyclo[4.3.1] cores

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Concise and very efficient synthesis of the N-methylwelwistatin tetracyclic core based on an anionic domino process

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Access to a welwitindolinone core using sequential cycloadditions

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Bridgehead enolates and bridgehead alkenes in a welwistatin model series

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Evolution of a synthetic strategy: total synthesis of (+/-)-welwitindolinone A isonitrile

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Total synthesis of (+/-)-welwitindolinone a isonitrile

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Enantioselective total syntheses of welwitindolinone A and fischerindoles I and G.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Aryllead(IV) reagents in synthesis: formation of the C11 quaternary center of N-methylwelwitindolinone C isothiocyanate.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4206695

Synthesis of (+/-)-puraquinonic acid: an inducer of cell differentiation

16 August 2018

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A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones We thank Professors Brauman, Stack, Trost, and Wender for many helpful discussions. C.G.E. is the recipient of an NSF Predoctoral Fellowship. J.D.B. g

16 August 2018

1 reference

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Oxidized welwitindolinones from terrestrial fischerella spp

16 August 2018

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12 December 2020

An Expedient Construction of Seven-Membered Rings Adjoining Aromatic Systems

1 reference

12 December 2020

A silver-catalyzed intramolecular amidation of saturated C--h bonds

1 reference

12 December 2020

Improved procedure for the oxidative cleavage of olefins by OsO4-NaIO4

1 reference

12 December 2020

Rapid synthesis of the N-methylwelwitindolinone skeleton

1 reference

12 December 2020

Rapid access to the Welwitindolinone alkaloid skeleton by cyclization of indolecarboxaldehyde substituted cyclohexanones

1 reference

12 December 2020

A synthesis of the welwistatin core

1 reference

12 December 2020

Silver-catalyzed intermolecular amination of C--H groups

1 reference

12 December 2020

Concise synthesis of the bicyclic scaffold of N-methylwelwitindolinone C isothiocyanate via an indolyne cyclization

1 reference

12 December 2020

Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

1 reference

12 December 2020

Total synthesis: Welwitindolinone is well worth it

1 reference

12 December 2020

Enabling the use of heterocyclic arynes in chemical synthesis

1 reference

12 December 2020

Progress toward the total synthesis of N-methylwelwitindolinone B isothiocyanate

1 reference

12 December 2020

A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA5087672

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25275668%20AND%20SRC:MED&resulttype=core&format=json

20 February 2020

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20 February 2020

PubMed publication ID

25275668

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25275668%20AND%20SRC:MED&resulttype=core&format=json