Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene (Q43165966)

15 November 2017

Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene (English)

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15 November 2017

4

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15 November 2017

Steven G Sethofer

1

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15 November 2017

Steven T Staben

series ordinal

2

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15 November 2017

Olivia Y Hung

series ordinal

3

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15 November 2017

language of work or name

English

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publication date

30 August 2008

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15 November 2017

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15 November 2017

10

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15 November 2017

19

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15 November 2017

4315-4318

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Cycloisomerization of 1,n-enynes: challenging metal-catalyzed rearrangements and mechanistic insights.

15 November 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Relativistic effects in homogeneous gold catalysis

25 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

PtCl2-catalyzed rearrangement of methylenecyclopropanes

25 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold(I)-catalyzed stereoselective olefin cyclopropanation.

25 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Au-catalyzed synthesis of (1Z,3E)-2-pivaloxy-1,3-dienes from propargylic pivalates

25 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Total synthesis of (+)-fawcettimine

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold-catalyzed intramolecular redox reaction of sulfinyl alkynes: efficient generation of alpha-oxo gold carbenoids and application in insertion into R--CO bonds.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold(I)-catalyzed oxidative rearrangements

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Synthesis of benzonorcaradienes by gold(I)-catalyzed [4+3] annulation.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold(I)-catalyzed cyclizations of silyl enol ethers: application to the synthesis of (+)-lycopladine A.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Platinum- and gold-catalyzed rearrangement reactions of propargyl acetates: total syntheses of (-)-alpha-cubebene, (-)-cubebol, sesquicarene and related terpenes

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Efficient synthesis of cyclopentenones from enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold(I)-catalyzed intramolecular acetylenic Schmidt reaction.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold(I)-catalyzed ring expansion of cyclopropanols and cyclobutanols

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Synthesis of 2-cyclopentenones by gold(I)-catalyzed Rautenstrauch rearrangement.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Carene terpenoids by gold-catalyzed cycloisomerization reactions

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Catalytic isomerization of 1,5-enynes to bicyclo[3.1.0]hexenes

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Catalytic regioselectivity control in ring-opening cycloisomerization of methylene- or alkylidenecyclopropyl ketones

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Platinum- and gold-catalyzed cycloisomerization reactions of hydroxylated enynes

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Palladium-catalyzed [3+2] intramolecular cycloaddition of alk-5-ynylidenecyclopropanes: a rapid, practical approach to bicyclo[3.3.0]octenes.

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

The application of cyclobutane derivatives in organic synthesis

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Gold-Catalyzed Synthesis of Bicyclo[4.3.0]nonadiene Derivatives via Tandem 6-endo-dig/Nazarov Cyclization of 1,6-Allenynes

15 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

(Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent

29 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2653418

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

3 November 2018

1 reference

12 December 2020

Molecular diversity through gold catalysis with alkynes

1 reference

12 December 2020

Gold-catalyzed organic reactions

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12 December 2020

Transition metal chemistry of cyclopropenes and cyclopropanes

1 reference

12 December 2020

Tandem gold(I)-catalyzed cyclization/electrophilic cyclopropanation of vinyl allenes

1 reference

12 December 2020

An Approach toward the Triquinane-Type Skeleton via Reagent-Controlled Skeletal Rearrangements. A Facile Method for Protection-Deprotection of Organomercurials, Tuning the Selectivity of Wagner-Meerwein Migrations, and a New Route to Annulated Lacto

1 reference

12 December 2020

AuCl-catalyzed synthesis of benzyl-protected substituted phenols: a formal [3+3] approach

1 reference

12 December 2020

Electrophilic cyclizations of vinylcyclopropanols to tethered aldehydes

1 reference

12 December 2020

Gold(I)-catalyzed divergence in the reactivity of 3-silyloxy 1,6-enynes: pinacol-terminated vs claisen-terminated cyclization cascades.

1 reference

12 December 2020

Gold(I)-catalyzed intermolecular cyclopropanation of enynes with alkenes: trapping of two different gold carbenes

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12 December 2020

Gold(I)-catalyzed synthesis of functionalized cyclopentadienes

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12 December 2020

Gold-catalyzed cyclization of enynes

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12 December 2020

Cationic gold(I) complexes: highly alkynophilic catalysts for the exo- and endo-cyclization of enynes

1 reference

12 December 2020

1,2-Alkyl migration as a key element in the invention of cascade reactions catalyzed by pi-acids

1 reference

12 December 2020

From sigma- to pi-electrophilic Lewis acids. Application to selective organic transformations

1 reference

12 December 2020

Catalyzed tandem reaction of 3-silyloxy-1,5-enynes consisting of cyclization and pinacol rearrangement

1 reference

12 December 2020

Synthesis of (-)-cubebol by face-selective platinum-, gold-, or copper-catalyzed cycloisomerization: evidence for chirality transfer

1 reference

12 December 2020

Total synthesis of platencin

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12 December 2020

The chemistry of cyclopropanols

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12 December 2020

Golden opportunities in stereoselective catalysis

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12 December 2020

Identifiers

DOI

10.1021/OL801760W

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15 November 2017

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15 November 2017

PubMed publication ID

18759435

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