New cardenolide and acylated lignan glycosides from the aerial parts of Asclepias curassavica (Q46452941)

22 December 2017

title

New cardenolide and acylated lignan glycosides from the aerial parts of Asclepias curassavica (English)

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22 December 2017

main subject

Asclepias curassavica

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(3S,5S,10R,13R,14S,17R)-14-hydroxy-13-methyl-17-(5-oxo-2H-furan-3-yl)-3-[(2R,5S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-1,2,3,4,5,6,7,8,9,11,12,15,16,17-tetradecahydrocyclopenta[a]phenanthrene-10-carbaldehyde

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[(1S,3R,5S,7R,9S,10S,12R,14R,15S,18R,19R,22S,23R)-10,22-dihydroxy-14-(hydroxymethyl)-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-9-yl] acetate

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[(1S,3R,5S,7R,9S,10S,12R,14R,15S,18R,19R,22S,23R)-10,14,22-trihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-9-yl] acetate

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16alpha-Acetoxy-10beta-hydroxy-19-norasclepin

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[(1S,3S,5S,7R,9R,10S,12S,14S,15R,18S,19S,20S,22R,23R)-20-acetyloxy-14-formyl-10,22-dihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-9-yl] acetate

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[(1S,3S,5S,7S,9S,10S,12R,14S,15S,18S,19S,20S,22S,23S)-14-formyl-9,10,22-trihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-20-yl] acetate

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(Z)-3-(3-methoxy-4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3,5-dimethoxy-4-hydroxybenzyl)tetrahydrofuran

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(1S,3R,5S,6R,8R,10S,12R,14R,15S,18R,19R,22S,23R)-5,6,22-trihydroxy-8,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,9,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosane-14-carbaldehyde

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(Z)-3-(3-methoxy-4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3-methoxy-4-hydroxybenzyl)tetrahydrofuran

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[(2S,3R,4R,5R,6S)-6-{[(1S,3aR,3bS,5aS,7S,9aR,9bR,11aS)-3a-hydroxy-9a,11a-dimethyl-1-(5-oxo-2H-furan-3-yl)-tetradecahydrocyclopenta[a]phenanthren-7-yl]oxy}-3,4,5-trihydroxyoxan-2-yl]methyl (2E)-3-(4-hydroxyphenyl)prop-2-enoate

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16alpha-Acetoxycalactin

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(1S,3R,5S,7R,9R,10R,12R,14R,15S,18R,19R,22S,23R)-10,22-dihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)spiro[4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosane-9,2'-5H-1,3-thiazole]-14-carbaldehyde

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16alpha-Acetoxycalotropin

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(1S,3R,5S,7R,9S,10R,12R,14R,15S,18R,19R,20R,22S,23R)-10,20,22-trihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)spiro[4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosane-9,2'-5H-1,3-thiazole]-14-carbaldehyde

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(E)-3-(3,5-dimethoxy-4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3,5-dimethoxy-4-hydroxybenzyl)tetrahydrofuran

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(E)-3-(3-methoxy-4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3-methoxy-4-hydroxybenzyl)tetrahydrofuran

1 reference

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(E)-3-(4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3,5-dimethoxy-4-hydroxybenzyl)tetrahydrofuran

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1 reference

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(3S,5S,8R,9S,10R,13R,14S,17R)-14-hydroxy-13-methyl-17-(5-oxo-2H-furan-3-yl)-3-[(2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy-1,2,3,4,5,6,7,8,9,11,12,15,16,17-tetradecahydrocyclopenta[a]phenanthrene-10-carbaldehyde

1 reference

[(1S,3S,5S,7R,9S,10R,12R,14R,15S,18R,19R,20R,22R,23R)-14-formyl-10,20,22-trihydroxy-7,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,6,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-9-yl] acetate

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1 reference

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[(1S,3R,5S,6R,8R,10S,12R,14R,15S,18R,19R,20R,22S,23R)-14-formyl-5,6,22-trihydroxy-8,18-dimethyl-19-(5-oxo-2H-furan-3-yl)-4,9,11-trioxahexacyclo[12.11.0.03,12.05,10.015,23.018,22]pentacosan-20-yl] acetate

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3beta-[[6-O-[3-(3,5-Dimethoxy-4-hydroxyphenyl)propenoyl]-beta-D-glucopyranosyl]oxy]-14-hydroxy-5alpha-card-20(22)-enolide

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2alpha,3beta-[Oxycarbonyl[(2S)-3-hydroxy-5beta-methyltetrahydrofuran-3beta,2beta-diyl]oxy]-14-hydroxy-19-oxo-5alpha-carda-20(22)-enolide

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3-[(3S,5S,8S,9S,10R,13R,14S,17R)-3,14-dihydroxy-10-(hydroxymethyl)-13-methyl-1,2,3,4,5,6,7,8,9,11,12,15,16,17-tetradecahydrocyclopenta[a]phenanthren-17-yl]-2H-furan-5-one

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16alpha-Hydroxyasclepin

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(2S)-2alpha-(3,5-Dimethoxy-4-hydroxyphenyl)-3beta-[6-O-[(E)-3-(3-methoxy-4-hydroxyphenyl)acryloyl]-beta-D-glucopyranosyloxymethyl]-4beta-(3,5-dimethoxy-4-hydroxybenzyl)tetrahydrofuran

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16alpha-Acetoxyasclepin

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6'-O-(4-Hydroxy-trans-cinnamoyl)desglucouzarin

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3

Toshio Miyase

1 reference

22 December 2017

author name string

Tsutomu Warashina

1

1 reference

22 December 2017

Kimiko Shikata

2

1 reference

22 December 2017

Satoshi Fujii

4

1 reference

22 December 2017

Tadataka Noro

5

1 reference

22 December 2017

language of work or name

English

1 reference

Chemical & Pharmaceutical Bulletin

publication date

2008

3 references

16 September 2022

16 September 2022

full work available at URL

https://www.jstage.jst.go.jp/article/cpb/56/8/56_8_1159/_pdf

1 reference

19 March 2024

https://api.unpaywall.org/v2/10.1248/cpb.56.1159?email=unpaywall_01@example.com

published in

Chemical & Pharmaceutical Bulletin

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22 December 2017

volume

56

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22 December 2017

issue

8

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22 December 2017

page(s)

1159-1163

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22 December 2017

https://api.unpaywall.org/v2/10.1248/cpb.56.1159?email=unpaywall_01@example.com

1 reference

19 March 2024

access restriction status

open access

1 reference

based on heuristic

inferred from online access status

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Identifiers

DOI

10.1248/CPB.56.1159

1 reference

22 December 2017

PubMed ID

18670118

1 reference

22 December 2017