A backbone lever-arm effect enhances polymer mechanochemistry. (Q51836140)

13 April 2018

title

A backbone lever-arm effect enhances polymer mechanochemistry. (English)

1 reference

13 April 2018

author

Stephen L Craig

5

1 reference

13 April 2018

author name string

Hope M Klukovich

1

1 reference

13 April 2018

Tatiana B Kouznetsova

2

1 reference

13 April 2018

Zachary S Kean

3

1 reference

13 April 2018

Jeremy M Lenhardt

4

1 reference

13 April 2018

publication date

23 December 2012

1 reference

13 April 2018

published in

Nature Chemistry

1 reference

13 April 2018

volume

5

1 reference

13 April 2018

issue

2

1 reference

13 April 2018

page(s)

110-114

1 reference

13 April 2018

Biasing reaction pathways with mechanical force

cites work

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Trapping a diradical transition state by mechanochemical polymer extension

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Unclicking the click: mechanically facilitated 1,3-dipolar cycloreversions

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

A mechanochemical approach to deracemization

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Force-induced activation of covalent bonds in mechanoresponsive polymeric materials

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Mechanically induced chemiluminescence from polymers incorporating a 1,2-dioxetane unit in the main chain

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Mechanically-induced chemical changes in polymeric materials

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Structure-mechanochemical activity relationships for cyclobutane mechanophores

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

21 January 2018

A molecular force probe.

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Adsorption-induced scission of carbon–carbon bonds

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

First principles dynamics and minimum energy pathways for mechanochemical ring opening of cyclobutene

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Understanding covalent mechanochemistry.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Force-activated reactivity switch in a bimolecular chemical reaction.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Direct observation of disulfide isomerization in a single protein

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Contrasting the individual reactive pathways in protein unfolding and disulfide bond reduction observed within a single protein.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Molecular stress relief through a force-induced irreversible extension in polymer contour length.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Force-reactivity property of a single monomer is sufficient to predict the micromechanical behavior of its polymer

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

The molecular elasticity of the extracellular matrix protein tenascin

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Dynamic strength of molecular adhesion bonds

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Probing the relation between force--lifetime--and chemistry in single molecular bonds

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Correction of systematic errors in single-molecule force spectroscopy with polymeric tethers by atomic force microscopy.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Chains are more flexible under tension.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Solvolytic ring-opening reactions of cyclopropyl bromides. An assessment of the Woodward-Hoffmann-DePuy rule

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Free energy profiles from single-molecule pulling experiments

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Kinetics from nonequilibrium single-molecule pulling experiments

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Intrinsic rates and activation free energies from single-molecule pulling experiments.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Force-dependent chemical kinetics of disulfide bond reduction observed with single-molecule techniques

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Method to derive restoring forces of strained molecules from kinetic measurements.

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Reactive Cross-Talk between Adjacent Tension-Trapped Transition States

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNCHEM.1540

Force-transformed free-energy surfaces and trajectory-shooting simulations reveal the mechano-stereochemistry of cyclopropane ring-opening reactions

21 January 2018

1 reference

12 December 2020

Quantum-chemical validation of the local assumption of chemomechanics for a unimolecular reaction

1 reference

12 December 2020

Polysaccharide elasticity governed by chair–boat transitions of the glucopyranose ring

1 reference

12 December 2020

Regiochemical effects on molecular stability: a mechanochemical evaluation of 1,4- and 1,5-disubstituted triazoles

1 reference

12 December 2020

gem-Dichlorocyclopropanes as abundant and efficient mechanophores in polybutadiene copolymers under mechanical stress

1 reference

12 December 2020

Chemical reactions modulated by mechanical stress: extended Bell theory

1 reference

12 December 2020

Activating catalysts with mechanical force

1 reference

12 December 2020

Mechanochemical transduction of externally applied forces to mechanophores

1 reference

12 December 2020

Single-molecule force spectroscopy of bimolecular reactions: system homology in the mechanical activation of ligand substitution reactions

1 reference

12 December 2020

Tension trapping of carbonyl ylides facilitated by a change in polymer backbone

1 reference

12 December 2020

Identifiers

DOI

10.1038/NCHEM.1540

1 reference

13 April 2018

Dimensions Publication ID

1026161105

0 references

1 reference

13 April 2018