Highly diastereoselective Csp3–Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds (Q61337066)

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17 January 2020

title

Highly diastereoselective Csp₃-Csp₂ Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds (English)

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17 January 2020

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17 January 2020

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Hendrik Zipse

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17 January 2020

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Paul Knochel

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17 January 2020

author name string

Tobias Thaler

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17 January 2020

Benjamin Haag

2

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17 January 2020

Andrei Gavryushin

3

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17 January 2020

Katrin Schober

4

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17 January 2020

Evelyn Hartmann

5

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17 January 2020

Peter Mayer

8

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17 January 2020

publication date

17 January 2010

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17 January 2020

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17 January 2020

volume

2

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17 January 2020

issue

2

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17 January 2020

page(s)

125-130

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Study of the Configuration Stability of the Carbon - Zinc Bond, Direct Measurement of Enantiomeric Ratios, and Tentative Assignment of the Absolute Configuration in Secondary Organozinc Halides We gratefully acknowledge the financial support provide

17 January 2020

cites work

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12 December 2020

Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine

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High yielding alkylations of unactivated sp3 and sp2 centres with alkyl-9-BBN reagents using an NHC-based catalyst: Pd-PEPPSI-IPrf

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The first Negishi cross-coupling reaction of two alkyl centers utilizing a Pd-N-heterocyclic carbene (NHC) catalyst

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Selected patented cross-coupling reaction technologies

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Zinc-catalyzed enantiospecific sp3-sp3 cross-coupling of alpha-hydroxy ester triflates with Grignard reagents

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12 December 2020

Catalytic asymmetric cross-couplings of racemic alpha-bromoketones with arylzinc reagents

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12 December 2020

Oxidative cross-coupling through double transmetallation: surprisingly high selectivity for palladium-catalyzed cross-coupling of alkylzinc and alkynylstannanes

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12 December 2020

Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds

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12 December 2020

A rationally designed universal catalyst for Suzuki-Miyaura coupling processes

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Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density

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Secondary alkyl halides in transition-metal-catalyzed cross-coupling reactions.

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Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy.

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12 December 2020

Efficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and Bromides

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12 December 2020

Asymmetric nickel-catalyzed Negishi cross-couplings of secondary alpha-bromo amides with organozinc reagents

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12 December 2020

Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents

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12 December 2020

Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl Halides

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12 December 2020

New insights into the classic chiral Grignard reagent (1R,2S,5R)-menthylmagnesium chloride

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12 December 2020

The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis A list of abbreviations can be found at the end of the article

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12 December 2020

Enantioselective nickel-catalyzed cross-coupling reactions of trialkynylindium reagents with racemic secondary benzyl bromides

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12 December 2020

Density-functional exchange-energy approximation with correct asymptotic behavior

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12 December 2020

Efficient cross-coupling of secondary alkyltrifluoroborates with aryl chlorides--reaction discovery using parallel microscale experimentation

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12 December 2020

Kumada–Corriu coupling of Grignard reagents, probed with a chiral Grignard reagent

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12 December 2020

Palladium-Catalyzed Reaction of Boronic Acids with Chiral and Racemic α-Bromo Sulfoxides

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12 December 2020

Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

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7 January 2021

Stereoselective Preparation and Reactions of Cycloalkylzinc Compounds

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7 January 2021

Self‐consistent molecular orbital methods. XXIII. A polarization‐type basis set for second‐row elements

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7 January 2021

6-31G* basis set for atoms K through Zn

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7 January 2021