Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes (Q34017510)

30 July 2017

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title

Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes (English)

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30 July 2017

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3

Stephen J Lippard

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30 July 2017

Simone Friedle

1

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30 July 2017

Erwin Reisner

series ordinal

2

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30 July 2017

publication date

20 May 2010

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30 July 2017

published in

Chemical Society Reviews

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30 July 2017

volume

39

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30 July 2017

issue

8

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30 July 2017

page(s)

2768-2779

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Carboxylate as the protonation site in (Peroxo)diiron(III) model complexes of soluble methane monooxygenase and related diiron proteins

30 July 2017

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9-Triptycenecarboxylate-Bridged Diiron(II) Complexes: Capture of the Paddlewheel Geometric Isomer

5 July 2018

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5 July 2018

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5 July 2018

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5 July 2018

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5 July 2018

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Synthesis and Characterization of a Ditriflate-Bridged, Diiron(II) Complex with Syn-N-Donor Ligands: [Fe(2)(μ-OTf)(2)(PIC(2)DET)(2)](BARF)(2)

5 July 2018

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5 July 2018

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5 July 2018

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Characterization of the arene-oxidizing intermediate in ToMOH as a diiron(III) species

5 July 2018

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Finding intermediates in the O2 activation pathways of non-heme iron oxygenases.

5 July 2018

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Substrate trafficking and dioxygen activation in bacterial multicomponent monooxygenases.

5 July 2018

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High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions

5 July 2018

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Synthesis and reactivity of Haloacetato derivatives of iron(II) including the crystal and the molecular structure of [Fe(CF3COOH)2(micro-CF3COO)2]n

5 July 2018

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The biochemistry of methane oxidation

5 July 2018

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X-ray Structure of a Hydroxylase−Regulatory Protein Complex from a Hydrocarbon-Oxidizing Multicomponent Monooxygenase, Pseudomonas sp. OX1 Phenol Hydroxylase † , ‡

5 July 2018

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Water induces a structural conversion and accelerates the oxygenation of carboxylate-bridged non-heme diiron enzyme synthetic analogues

5 July 2018

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Mechanistic studies of the oxidative N-dealkylation of a substrate tethered to carboxylate-bridged diiron(II) complexes, [Fe2(mu-O2CAr(Tol))2(O2CAr(Tol))2(N,N-Bn2en)2]

5 July 2018

1 reference

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Stalking intermediates in oxygen activation by iron enzymes: motivation and method

5 July 2018

1 reference

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Dioxygen-initiated oxidation of heteroatomic substrates incorporated into ancillary pyridine ligands of carboxylate-rich diiron(II) complexes

5 July 2018

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Synthesis, characterization, and preliminary oxygenation studies of benzyl- and ethyl-substituted pyridine ligands of carboxylate-rich diiron(II) complexes

5 July 2018

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Iron substitution for sodium in a carboxylate-bridged, heterodinuclear sodium-iron complex

5 July 2018

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5 July 2018

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The Leeuwenhoek Lecture 2000 the natural and unnatural history of methane-oxidizing bacteria

5 July 2018

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Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species

5 July 2018

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Crystal structure of a membrane-bound metalloenzyme that catalyses the biological oxidation of methane

5 July 2018

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Synthetic models for non-heme carboxylate-bridged diiron metalloproteins: strategies and tactics.

5 July 2018

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Radical initiation in the class I ribonucleotide reductase: long-range proton-coupled electron transfer?

5 July 2018

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Dioxygen Activation and Methane Hydroxylation by Soluble Methane Monooxygenase: A Tale of Two Irons and Three Proteins A list of abbreviations can be found in Section 7.

5 July 2018

1 reference

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Xenon and halogenated alkanes track putative substrate binding cavities in the soluble methane monooxygenase hydroxylase

5 July 2018

1 reference

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Dendritic Encapsulation of Function: Applying Nature's Site Isolation Principle from Biomimetics to Materials Science

5 July 2018

1 reference

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The catalytic pathway of cytochrome p450cam at atomic resolution

5 July 2018

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5 July 2018

Methanotrophic bacteria

1 reference

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A planar carboxylate-rich tetraironII complex and its conversion to linear triironII and paddlewheel diironII complexes

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Influence of steric hindrance on the core geometry and sulfoxidation chemistry of carboxylate-rich diiron(II) complexes

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Synthesis and oxidation of carboxylate-bridged diiron(II) complexes with substrates tethered to primary alkyl amine ligands

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Water affects the stereochemistry and dioxygen reactivity of carboxylate-rich diiron(II) models for the diiron centers in dioxygen-dependent non-heme enzymes

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Reactions of the peroxo intermediate of soluble methane monooxygenase hydroxylase with ethers

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Catalytically active mu-Oxodiiron(IV) oxidants from Iron(III) and dioxygen.

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Crystal structure of the toluene/o-xylene monooxygenase hydroxylase from Pseudomonas stutzeri OX1. Insight into the substrate specificity, substrate channeling, and active site tuning of multicomponent monooxygenases

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Modeling the syn disposition of nitrogen donors at the active sites of carboxylate-bridged diiron enzymes. Enforcing dinuclearity and kinetic stability with a 1,2-diethynylbenzene-based ligand

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Iron complexes capped with dendrimer-appended triazacyclononanes as the novel spatially encumbered models of non-heme iron proteins

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Modeling dioxygen-activating centers in non-heme diiron enzymes: carboxylate shifts in diiron(II) complexes supported by sterically hindered carboxylate ligands

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Functional mimic of dioxygen-activating centers in non-heme diiron enzymes: mechanistic implications of paramagnetic intermediates in the reactions between diiron(II) complexes and dioxygen

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Oxidative N-dealkylation of a carboxylate-bridged diiron(II) precursor complex by reaction with O2 affords the elusive [Fe2(mu-OH)2(mu-O2CR)](3+) core of soluble methane monooxygenase hydroxylase

29 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2909375

Protein Radicals in Enzyme Catalysis

29 October 2018

1 reference

12 December 2020

Hydroxylation of methane by non-heme diiron enzymes: molecular orbital analysis of C-H bond activation by reactive intermediate Q

1 reference

12 December 2020

Unusual peroxo intermediates in the reaction of dioxygen with carboxylate-bridged diiron(II,II) paddlewheel complexes

1 reference

12 December 2020

Structural and spectroscopic characterization of (mu-hydroxo or mu-oxo)(mu-peroxo)diiron(III) complexes: models for peroxo intermediates of non-heme diiron proteins

1 reference

12 December 2020

Ferritins: dynamic management of biological iron and oxygen chemistry

1 reference

12 December 2020

Molecular recognition in the selective oxygenation of saturated C-H bonds by a dimanganese catalyst

1 reference

12 December 2020

Correlating structure with function in bacterial multicomponent monooxygenases and related diiron proteins

1 reference

12 December 2020

A Bulky Benzoate Ligand for Modeling the Carboxylate-Rich Active Sites of Non-Heme Diiron Enzymes.

1 reference

12 December 2020

Dioxygen Activation and Methane Hydroxylation by Soluble Methane Monooxygenase: A Tale of Two Irons and Three Proteins

1 reference

12 December 2020

Gating Effects of Component B on Oxygen Activation by the Methane Monooxygenase Hydroxylase Component

1 reference

12 December 2020

Transient intermediates of the methane monooxygenase catalytic cycle

1 reference

12 December 2020

An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

1 reference

12 December 2020

Identifiers

DOI

10.1039/C003079C

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30 July 2017

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30 July 2017

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