Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis (Q35127763)

6 August 2017

title

Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis (English)

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6 August 2017

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J Du Bois

1

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6 August 2017

publication date

1 July 2011

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Organic Process Research & Development

6 August 2017

published in

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6 August 2017

volume

15

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6 August 2017

issue

4

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6 August 2017

page(s)

758-762

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Functionalization of carbon-hydrogen bonds through transition metal carbenoid insertion.

6 August 2017

cites work

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Catalytic C-H amination: recent progress and future directions

13 July 2018

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Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity

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Catalytic carbene insertion into C-H bonds

13 July 2018

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Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination

13 July 2018

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Synthesis of 1,3-diamines through rhodium-catalyzed C-H insertion

13 July 2018

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Carbon-heteroatom bond formation catalysed by organometallic complexes

13 July 2018

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Coinage metal catalyzed C-H bond functionalization of hydrocarbons.

13 July 2018

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Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450.

13 July 2018

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A chiral rhodium carboxamidate catalyst for enantioselective C-H amination

13 July 2018

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N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions

13 July 2018

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Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

13 July 2018

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(+)-saxitoxin: a first and second generation stereoselective synthesis

13 July 2018

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Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights

13 July 2018

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A stereoselective synthesis of (-)-tetrodotoxin

13 July 2018

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Organosilanes in synthesis: application to an enantioselective synthesis of methyl-l-callipeltose

13 July 2018

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Understanding and exploiting C-H bond activation

13 July 2018

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Inverted regioselectivity of C-H amination: Unexpected oxidation at beta- rather than gamma-C-H

13 July 2018

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Ruthenium-catalyzed hydroxylation of unactivated tertiary C-H bonds

27 September 2018

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N-heterocycle construction via cyclic sulfamidates. Applications in synthesis

27 September 2018

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27 September 2018

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Iterative multifunctionalization of unactivated C-H bonds in piperidines by way of intramolecular Rh(II)-catalyzed aminations

27 September 2018

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Toward a synthetically useful stereoselective C-H amination of hydrocarbons

27 September 2018

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Oxaziridine-mediated catalytic hydroxylation of unactivated 3 degrees C-H bonds using hydrogen peroxide

27 September 2018

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Expanding the scope of C-H amination through catalyst design

27 September 2018

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Novel iminium ion equivalents prepared through C-H oxidation for the stereocontrolled synthesis of functionalized propargylic amine derivatives

27 September 2018

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Enantioselective synthesis of the bromopyrrole alkaloids manzacidin A and C by stereospecific C-h bond oxidation

27 September 2018

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Callipeltoside a: total synthesis, assignment of the absolute and relative configuration, and evaluation of synthetic analogues

27 September 2018

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A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones We thank Professors Brauman, Stack, Trost, and Wender for many helpful discussions. C.G.E. is the recipient of an NSF Predoctoral Fellowship. J.D.B. g

27 September 2018

1 reference

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Introduction to selective functionalization of C-H bonds

27 September 2018

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12 December 2020

C-H bond functionalization in complex organic synthesis

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12 December 2020

Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations

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12 December 2020

Enantioselective C-H amination using cationic ruthenium(II)-pybox catalysts

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12 December 2020

A silver-catalyzed intramolecular amidation of saturated C--h bonds

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12 December 2020

Efficient diastereoselective intermolecular rhodium-catalyzed C-H amination

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12 December 2020

[Fe(F(20)TPP)Cl] catalyzed intramolecular C-N bond formation for alkaloid synthesis using aryl azides as nitrogen source

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12 December 2020

A Synthesis of l-Vancosamine Derivatives from Non-Carbohydrate Precursors by a Short Sequence Based on the Marshall, McDonald, and Du Bois Reactions

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12 December 2020

Acyclic Stereocontrol in the Catalytic C−H Amination of Benzylic Methylene Groups

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12 December 2020

Transition-metal-free intermolecular amination of sp3 C-H bonds with sulfonamides

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12 December 2020

New aspects of catalytic intramolecular C-H amination: unexpected formation of a seven-membered ring in nitrogen-containing systems

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12 December 2020

Copper-nitrene complexes in catalytic C-H amination

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12 December 2020

Expanding the substrate scope for C-H amination reactions: oxidative cyclization of urea and guanidine derivatives

1 reference

12 December 2020

Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds

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12 December 2020

De novo synthesis of Troc-protected amines: intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates

1 reference

12 December 2020

Silver-catalyzed intermolecular amination of C--H groups

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12 December 2020

Stereochemical models for rh-catalyzed amination reactions of chiral sulfamates

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12 December 2020

Rh-catalyzed amination of ethereal Calpha-H bonds: a versatile strategy for the synthesis of complex amines

1 reference

12 December 2020

Dirhodium(II)-catalyzed intramolecular C-H amination of aryl azides

1 reference

12 December 2020

Amidation of saturated C-H bonds catalyzed by electron-deficient ruthenium and manganese porphyrins. A highly catalytic nitrogen atom transfer process

1 reference

12 December 2020

Highly diastereo- and enantioselective intramolecular amidation of saturated C-H bonds catalyzed by ruthenium porphyrins

1 reference

12 December 2020

Catalytic enantio- and diastereoselective alkylations with cyclic sulfamidates

1 reference

12 December 2020

Identifiers

DOI

10.1021/OP200046V

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6 August 2017

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6 August 2017

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