Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV. (Q38206709)

31 August 2017

title

Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV. (English)

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31 August 2017

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Franziska Schoenebeck

series ordinal

2

object named as

Franziska Schoenebeck

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Karl J Bonney

object named as

Karl J Bonney

series ordinal

1

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publication date

1 September 2014

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31 August 2017

published in

Chemical Society Reviews

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31 August 2017

volume

43

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31 August 2017

issue

18

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31 August 2017

page(s)

6609-6638

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Discovery of an α-amino C-H arylation reaction using the strategy of accelerated serendipity

31 August 2017

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Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions

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Formation of anionic palladium(0) complexes ligated by the trifluoroacetate ion and their reactivity in oxidative addition

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21 January 2018

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Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation

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DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)-H activation: role of the nature of the base and the phosphine

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Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups: method and mechanistic study

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Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

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21 January 2018

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Organopalladium(IV) chemistry

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Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates

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Bimetallic reductive elimination from dinuclear Pd(III) complexes

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21 January 2018

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Subtle balance of ligand steric effects in Stille transmetalation.

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Insights into the elementary steps in Negishi coupling through kinetic investigations.

21 January 2018

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Kumada–Corriu coupling of Grignard reagents, probed with a chiral Grignard reagent

21 January 2018

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Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate

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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

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Recent advances in the transition metal-catalyzed twofold oxidative C-H bond activation strategy for C-C and C-N bond formation

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Propane activation by palladium complexes with chelating bis(NHC) ligands and aerobic cooxidation

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Palladium Round Trip in the Negishi Coupling of trans-[PdMeCl(PMePh2)2] with ZnMeCl: An Experimental and DFT Study of the Transmetalation Step

21 January 2018

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Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme

21 January 2018

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Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3Catalyzed bytrans-[PdR1IL2] (R1= C6Cl2F3; R2= Vinyl, 4-Methoxyphenyl; L = AsPh3)

21 January 2018

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A theoretical DFT-based and experimental study of the transmetalation step in Au/Pd-mediated cross-coupling reactions.

21 January 2018

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Stille coupling involving bulky groups feasible with gold cocatalyst

21 January 2018

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Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes

21 January 2018

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C-C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment

21 January 2018

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Transmetallation versus β-hydride elimination: the role of 1,4-benzoquinone in chelation-controlled arylation reactions with arylboronic acids

21 January 2018

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Bite angle effects of diphosphines in C-C and C-X bond forming cross coupling reactions.

21 January 2018

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Slow reductive elimination from arylpalladium parent amido complexes

21 January 2018

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Reductive elimination from arylpalladium cyanide complexes

21 January 2018

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Kinetic and density functional studies on alkyl-carbene elimination from Pd(II) heterocylic carbene complexes: a new type of reductive elimination with clear implications for catalysis

21 January 2018

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Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations

21 January 2018

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Nucleophile-catalyzed, facile, and highly selective C-H activation of fluoroform with Pd(II).

21 January 2018

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N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation

21 January 2018

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Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

21 January 2018

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Intramolecular C-H activation by alkylpalladium(II) complexes: insights into the mechanism of the palladium-catalyzed arylation reaction

21 January 2018

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Direct palladium-catalyzed C-2 and C-3 arylation of indoles: a mechanistic rationale for regioselectivity

21 January 2018

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Understanding reactivity and stereoselectivity in palladium-catalyzed diastereoselective sp3 C-H bond activation: intermediate characterization and computational studies.

21 January 2018

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Enantioselective and Diastereoselective Tsuji-Trost Allylic Alkylation of Lactones: An Experimental and Computational Study

21 January 2018

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Origin of Selectivity of Tsuji-Trost Allylic Alkylation of Lactones: Highly Ordered Transition States with Lithium-Containing Enolates

21 January 2018

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The oxidative addition of lodomethane to [PdMe2(bpy)] and the X-ray structure of the organopalladium(IV) product fac-[PdMe3(bpy)l](bpy = 2,2′-bipyridyl)

21 January 2018

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Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination

21 January 2018

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Synthetic and computational studies of the palladium(IV) system Pd(alkyl)(aryl)(alkynyl)(bidentate)(triflate) exhibiting selectivity in C-C reductive elimination

21 January 2018

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Mechanism of C-F reductive elimination from palladium(IV) fluorides

21 January 2018

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A fluoride-derived electrophilic late-stage fluorination reagent for PET imaging.

21 January 2018

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Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation

21 January 2018

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Combined experimental and theoretical study of the mechanism and enantioselectivity of palladium- catalyzed intermolecular Heck coupling.

21 January 2018

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Oxidative Addition of Aryl Halides to Palladium(0) Complexes: A Density-Functional Study Including Solvation

21 January 2018

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Mechanism of Pd-Catalyzed Ar–Ar Bond Formation Involving Ligand-Directed C–H Arylation and Diaryliodonium Oxidants: Computational Studies of Orthopalladation at Binuclear Pd(II) Centers, Oxidation To Form Binuclear Palladium(III) Species, and Ar?

21 January 2018

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Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage

21 January 2018

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On the role of anionic ligands in the site-selectivity of oxidative C–H functionalization reactions of arenes

21 January 2018

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Controlling Site Selectivity in Pd-Catalyzed Oxidative Cross-Coupling Reactions

21 January 2018

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Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

21 January 2018

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Participation of Carbonyl Oxygen in Carbon–Carboxylate Bond-Forming Reductive Elimination from Palladium

21 January 2018

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Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes

21 January 2018

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What Makes for a Bad Catalytic Cycle? A Theoretical Study on the Suzuki−Miyaura Reaction within the Energetic Span Model

21 January 2018

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Synthesis and X-ray Structural Characterization of Two Unbridged Diplatinum(III) Compounds: cis-andtrans-Bis[bis(1-imino-1-methoxyethane)trichloroplatinum(III)]. Transient Species in the Oxidation of Platinum(II) to Platinum(IV)

21 January 2018

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21 January 2018

Identifiers

DOI

10.1039/C4CS00061G

1 reference

31 August 2017

1 reference