Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation (Q33645846)

28 July 2017

1 reference

title

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation (English)

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28 July 2017

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2

Robert G Bergman

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28 July 2017

Denise A Colby

1

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28 July 2017

Jonathan A Ellman

series ordinal

3

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28 July 2017

publication date

1 February 2010

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28 July 2017

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28 July 2017

volume

110

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28 July 2017

issue

2

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28 July 2017

page(s)

624-655

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Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation

28 July 2017

cites work

1 reference

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21 June 2018

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Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation

21 June 2018

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Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes.

21 June 2018

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Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation

21 June 2018

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A general and efficient method for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles

21 June 2018

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Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation

21 June 2018

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Heterocyclic carbenes: synthesis and coordination chemistry.

21 June 2018

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Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation

21 June 2018

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Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight

21 June 2018

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The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization

21 June 2018

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Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

21 June 2018

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Copper-catalyzed arylation and alkenylation of polyfluoroarene C-H bonds

21 June 2018

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Copper-catalyzed arylation of heterocycle C-H bonds

21 June 2018

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Direct transition metal-catalyzed functionalization of heteroaromatic compounds

21 June 2018

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Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation

21 June 2018

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Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation

21 June 2018

1 reference

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Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

21 June 2018

1 reference

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Synthesis of heterocycles via palladium-catalyzed oxidative addition.

21 June 2018

1 reference

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COPASI--a COmplex PAthway SImulator

21 June 2018

1 reference

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Catalytic intermolecular direct arylation of perfluorobenzenes.

21 June 2018

1 reference

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Analysis of the reactions used for the preparation of drug candidate molecules

21 June 2018

1 reference

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Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation

21 June 2018

1 reference

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Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I).

21 June 2018

1 reference

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A solution to the 2-pyridyl organometallic cross-coupling problem: regioselective catalytic direct arylation of pyridine N-oxides.

21 June 2018

1 reference

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Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Total synthesis of (-)-incarvilline, (+)-incarvine C, and (-)-incarvillateine

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Double-chelation-assisted Rh-catalyzed intermolecular hydroacylation between salicylaldehydes and 1,4-penta- or 1,5-hexadienes

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

A stereoselective synthesis of (-)-tetrodotoxin

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rh(I)-catalyzed direct ortho-alkenylation of aromatic ketimines with alkynes and its application to the synthesis of isoquinoline derivatives.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Synthesis of a Tricyclic Mescaline Analogue by Catalytic C−H Bond Activation

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Catalytic C-h/olefin coupling

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Chelation-assisted carbon-hydrogen and carbon-carbon bond activation by transition metal catalysts

21 June 2018

1 reference

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Understanding and exploiting C-H bond activation

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Application of Rh(I)-catalyzed C-H bond activation to the ring opening of 2-cycloalkenones in the presence of amines

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rhodium-catalyzed direct oxidative carbonylation of aromatic C-H bond with CO and alcohols.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Carbon-hydrogen bond functionalization approach for the synthesis of fluorenones and ortho-arylated benzonitriles

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rhodium-catalyzed oxidative coupling between salicylaldehydes and internal alkynes with C-H bond cleavage to produce 2,3-disubstituted chromones.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Metal-organic cooperative catalysis in C-H and C-C bond activation and its concurrent recovery

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Palladium-catalyzed direct C-h arylation of N-iminopyridinium ylides: application to the synthesis of (+/-)-anabasine

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

A rhodium-catalyzed C-H activation/cycloisomerization tandem

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rh-catalyzed cyclization of diynes and enynes initiated by carbonyl-directed activation of aromatic and vinylic C-H bonds.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes via regioselective C-H bond cleavage.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Cationic Rh(I)/modified-BINAP-catalyzed reactions of carbonyl compounds with 1,6-diynes leading to dienones and ortho-functionalized aryl ketones.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Organometallic chemistry: C-H activation.

30 October 2018

1 reference

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An efficient waste-free oxidative coupling via regioselective C-H bond cleavage: Rh/Cu-catalyzed reaction of benzoic acids with alkynes and acrylates under air.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Combined C-H activation/cope rearrangement as a strategic reaction in organic synthesis: total synthesis of (-)-colombiasin a and (-)-elisapterosin B.

30 October 2018

1 reference

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Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation

30 October 2018

1 reference

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Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

30 October 2018

1 reference

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Insertion of polar and nonpolar unsaturated molecules into carbon-rhenium bonds generated by C-H bond activation: synthesis of phthalimidine and indene derivatives

30 October 2018

1 reference

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An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2.

30 October 2018

1 reference

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The neuroprotective action of JNK3 inhibitors based on the 6,7-dihydro-5H-pyrrolo[1,2-a]imidazole scaffold

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Annulation of aromatic imines via directed C-H bond activation

30 October 2018

1 reference

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Recyclable self-assembly-supported catalytic system for orthoalkylation.

30 October 2018

1 reference

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Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile.

30 October 2018

1 reference

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Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar-Rh(III) complexes assembled in situ

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Intermolecular coupling of alkenes to heterocycles via C-H bond activation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Theoretical studies of the oxidative addition of azolium salts to a model Wilkinson's catalyst

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Ruthenium- and rhodium-catalyzed direct carbonylation of the ortho C-H bond in the benzene ring of N-arylpyrazoles

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation

30 October 2018

1 reference

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Formation and stability of N-heterocyclic carbenes in water: the carbon acid pKa of imidazolium cations in aqueous solution

30 October 2018

1 reference

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A new solvent system for recycling catalysts for chelation-assisted hydroacylation of olefins with primary alcohols

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Catalytic Intermolecular Ortho-Arylation of Phenols

30 October 2018

1 reference

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Ruthenium-catalyzed C-H/CO/Olefin coupling reaction of N-arylpyrazoles. Extraordinary reactivity of N-arylpyrazoles toward carbonylation at C-H bonds

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Construction of pyridine rings by metal-mediated [2 + 2 + 2] cycloaddition.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine

30 October 2018

1 reference

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Facile synthesis of 2,5-diarylthiazoles via palladium-catalyzed tandem C-H substitutions. Design of tunable light emission and liquid crystalline characteristics

30 October 2018

1 reference

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Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Enantioselective synthesis of the bromopyrrole alkaloids manzacidin A and C by stereospecific C-h bond oxidation

30 October 2018

1 reference

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Ru3(CO)12-catalyzed C-H/CO/olefin coupling of N-pyridylindolines. Direct carbonylation at a C-H bond delta to the pyridine nitrogen

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole

30 October 2018

1 reference

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Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate

30 October 2018

1 reference

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Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

The Catalytic Alkylation of Aromatic Imines by Wilkinson's Complex: The Domino Reaction of Hydroacylation and ortho-Alkylation This work was supported by the Brain Korea 21 Project, the Yonsei University Faculty Research Grant (1999), and the KOSEF (

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

A Highly Active Catalyst System for Intermolecular Hydroacylation This work was supported by the Brain Korea 21 Project

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Iridium(III)-Induced Isomerization of 2-Substituted Pyridines to N-Heterocyclic Carbenes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Microwave-Assisted C−H Bond Activation: A Rapid Entry into Functionalized Heterocycles

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2820156

Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds

10 December 2018

1 reference

12 December 2020

Polymer support assisted selective functionalization of azoles using a palladium-catalyzed coupling reaction

1 reference

12 December 2020

C-H and C-C bond activation of primary amines through dehydrogenation and transimination

1 reference

12 December 2020

1 reference

12 December 2020

Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects

1 reference

12 December 2020

[Ir(4)(CO)(12)]-catalyzed coupling reaction of imidazoles with aldehydes in the presence of a hydrosilane to give 2-substituted imidazoles

1 reference

12 December 2020

Metal-Mediated Reductive Hydrodehalogenation of Organic Halides

1 reference

12 December 2020

Double-chelation-assisted Rh-catalyzed intermolecular hydroacylation

1 reference

12 December 2020

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization

1 reference

12 December 2020

Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes

1 reference

12 December 2020

Transition-metal-catalyzed reactions involving imidazolium salt/N-heterocyclic carbene couples as substrates

1 reference

12 December 2020

Ortho alkylation of aromatic ketimine with functionalized alkene by Rh(I) catalyst

1 reference

12 December 2020

Allocolchicinoid synthesis via direct arylation

1 reference

12 December 2020

Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation

1 reference

12 December 2020

C-H bond functionalization in complex organic synthesis

1 reference

12 December 2020

Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines

1 reference

12 December 2020

Recyclable self-assembly-supported catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol

1 reference

12 December 2020

Platinum-catalyzed intramolecular asymmetric hydroarylation of unactivated alkenes with indoles

1 reference

12 December 2020

Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis

1 reference

12 December 2020

Stabilization of NH tautomers of quinolines by osmium and ruthenium

1 reference

12 December 2020

Palladium-catalyzed cross-coupling reactions of diazine N-oxides with aryl chlorides, bromides, and iodides

1 reference

12 December 2020

Synthesis of tricyclic heterocycles via a tandem aryl alkylation/heck coupling sequence

1 reference

12 December 2020

The catalytic cross-coupling of unactivated arenes

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12 December 2020

Elements of regiocontrol in palladium-catalyzed oxidative arene cross-coupling

1 reference

12 December 2020

Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin

1 reference

12 December 2020

Oxidative coupling of arylboronic acids with arenes via Rh-catalyzed direct C-H arylation

1 reference

12 December 2020

Rhodium-catalyzed one-pot synthesis of substituted pyridine derivatives from alpha,beta-unsaturated ketoximes and alkynes

1 reference

12 December 2020

Rh-catalyzed carbonyl hydroacylation: an enantioselective approach to lactones

1 reference

12 December 2020

Pd(II)-catalyzed enantioselective activation of C(sp2)-H and C(sp3)-H bonds using monoprotected amino acids as chiral ligands

1 reference

12 December 2020

Rhodium-catalyzed regioselective C-H functionalization via decarbonylation of acid chlorides and C-H bond activation under phosphine-free conditions

1 reference

12 December 2020

Palladium-catalyzed C-H functionalization of pyridine N-oxides: highly selective alkenylation and direct arylation with unactivated arenes

1 reference

12 December 2020

Efficient and selective hydroacylation of 1-alkynes with aldehydes by a chelation-assisted catalytic system

1 reference

12 December 2020

N-heterocyclic carbenes: a new concept in organometallic catalysis

1 reference

12 December 2020

The Catalytic Intermolecular Orthoarylation of Phenols

1 reference

12 December 2020

Transition Metal Catalyzed Coupling Reactions under C-H Activation

1 reference

12 December 2020

Identifiers

DOI

10.1021/CR900005N

1 reference

28 July 2017

1 reference

28 July 2017

1 reference