Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners (Q34788016)

4 August 2017

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title

Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners (English)

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4 August 2017

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Ranjan Jana

1

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4 August 2017

Tejas P Pathak

series ordinal

2

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4 August 2017

Matthew S Sigman

series ordinal

3

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4 August 2017

publication date

14 February 2011

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4 August 2017

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4 August 2017

volume

111

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4 August 2017

issue

3

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4 August 2017

page(s)

1417-1492

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Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

4 August 2017

cites work

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Alkyl-alkyl Suzuki cross-coupling of unactivated secondary alkyl chlorides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Asymmetric alkyl-alkyl cross-couplings of unactivated secondary alkyl electrophiles: stereoconvergent Suzuki reactions of racemic acylated halohydrins

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R-M (M = MgX', ZnX').

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Synthesis of (S)-jamaicamide C carboxylic acid

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium-catalyzed hydroalkylation of styrenes with organozinc reagents to form carbon-carbon sp3-sp3 bonds under oxidative conditions

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Zn-mediated, Pd-catalyzed cross-couplings in water at room temperature without prior formation of organozinc reagents

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Cross-coupling of alkenyl/aryl carboxylates with Grignard reagent via Fe-catalyzed C-O bond activation

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

A versatile catalyst system for Suzuki-Miyaura cross-coupling reactions of C(sp(2))-tosylates and mesylates

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Studies for the synthesis of xenicane diterpenes. A stereocontrolled total synthesis of 4-hydroxydictyolactone

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Secondary alkyl halides in transition-metal-catalyzed cross-coupling reactions.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Nickel-catalyzed Negishi cross-couplings of secondary nucleophiles with secondary propargylic electrophiles at room temperature

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis of (-)-kendomycin

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Efficient cross-coupling of secondary alkyltrifluoroborates with aryl chlorides--reaction discovery using parallel microscale experimentation

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Synthesis of 5-fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Density functional theory studies of negishi alkyl-alkyl cross-coupling reactions catalyzed by a methylterpyridyl-Ni(I) complex

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Concise asymmetric total synthesis of scyphostatin, a potent inhibitor of neutral sphingomyelinase

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Preparation of organometallic compounds from highly reactive metal powders

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Alkyl-alkyl suzuki cross-couplings of unactivated secondary alkyl halides at room temperature

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Organotrifluoroborates: protected boronic acids that expand the versatility of the Suzuki coupling reaction

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis, structure revision, and absolute configuration of (-)-brevenal

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Oxidative cross-coupling through double transmetallation: surprisingly high selectivity for palladium-catalyzed cross-coupling of alkylzinc and alkynylstannanes

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Synthesis of functionalized organotrifluoroborates via the 1,3-dipolar cycloaddition of azides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Synthesis of functionalized organotrifluoroborates via halomethyltrifluoroborates

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Kumada coupling of aryl and vinyl tosylates under mild conditions

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Reporter gene imaging: potential impact on therapy.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

The first Negishi cross-coupling reaction of two alkyl centers utilizing a Pd-N-heterocyclic carbene (NHC) catalyst

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium-catalyzed cross-coupling reactions in total synthesis

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis of brevetoxin B.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Catalysts for Cross-Coupling Reactions with Non-activated Alkyl Halides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Iron-catalyzed reactions in organic synthesis

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis of kendomycin: a macro-C-glycosidation approach

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Phosphaadamantanes as ligands for palladium catalyzed cross-coupling chemistry: library synthesis, characterization, and screening in the Suzuki coupling of alkyl halides and tosylates containing beta-hydrogens with boronic acids and alkylboranes

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Positron emission tomography and gene therapy: basic concepts and experimental approaches for in vivo gene expression imaging.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Catalysis-based enantioselective total synthesis of the macrocyclic spermidine alkaloid isooncinotine

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Copper-mediated, palladium-catalyzed coupling of thiol esters with aliphatic organoboron reagents

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Asymmetric catalysis in complex target synthesis

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total syntheses of amphidinolide T1, T3, T4, and T5

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Antitumour polycyclic acridines. Palladium(0) mediated syntheses of quino[4,3,2-kl]acridines bearing peripheral substituents as potential telomere maintenance inhibitors

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

A Formal Total Synthesis of the Salicylihalamides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Highly functionalized organomagnesium reagents prepared through halogen-metal exchange

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Studies on the biosynthesis of cholesterol. 5. Biosynthesis of squalene from DL-3-hydroxy-3-methyl [2-14C] pentano-5-lactone

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Formation of carbon--carbon bonds under catalysis by transition-metal nanoparticles

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

An efficient synthesis of 2-substituted 6-methylpurine bases and nucleosides by Fe- or Pd-catalyzed cross-coupling reactions of 2,6-dichloropurines

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Catalytic enantioselective hydroboration of cyclopropenes

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium-catalyzed alkynylation.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Pd-catalyzed carbonylative cross-coupling reactions by triorganoindiums: highly efficient transfer of organic groups attached to indium under atmospheric pressure

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Boronic acids: new coupling partners in room-temperature Suzuki reactions of alkyl bromides. Crystallographic characterization of an oxidative-addition adduct generated under remarkably mild conditions

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total syntheses of [17]- and [18]dehydrodesoxyepothilones B via a concise ring-closing metathesis-based strategy: correlation of ring size with biological activity in the epothilone series

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Asymmetric crotylation reactions in synthesis of polypropionate-derived macrolides: application to total synthesis of oleandolide

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

PET imaging of gene expression

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis of (-)-callystatin A.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Alkylboranes in the Suzuki-Miyaura Coupling: Stereochemical and Mechanistic Studies

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Suzuki reaction of vinyl triflates from six- and seven-membered N-alkoxycarbonyl lactams with boronic acids and esters.

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Synthesis of unnatural amino acids via Suzuki cross-coupling of enantiopure vinyloxazolidine derivatives

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Oxidative cleavage of .alpha.-keto, .alpha.-hydroxy, and .alpha.-halo ketones, esters, and carboxylic acids by superoxide

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Pd-Catalyzed Enantioselective Allyl−Allyl Cross-Coupling

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Direct B-alkyl Suzuki-Miyaura cross-coupling of 2-halopurines. Practical synthesis of ST1535, a potent adenosine A2A receptor antagonist.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

The fine balance between one cross-coupling and two beta-hydride elimination pathways: a DFT mechanistic study of Ni(pi-allyl)(2)-catalyzed cross-coupling of alkyl halides and alkyl Grignard reagents

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Total synthesis of kapakahine E and F.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Anguinomycins and derivatives: total syntheses, modeling, and biological evaluation of the inhibition of nucleocytoplasmic transport

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Nickel N-heterocyclic carbene catalyst for cross-coupling of neopentyl arenesulfonates with methyl and primary alkyl grignard reagents

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Application of Negishi cross-coupling to the synthesis of the cyclic tripeptides OF4949-III and K-13.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Ni-catalyzed Sonogashira coupling of nonactivated alkyl halides: orthogonal functionalization of alkyl iodides, bromides, and chlorides

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Enantioselective total synthesis of the potent anti-inflammatory (+)-myrrhanol A.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Revealing a second transmetalation step in the Negishi coupling and its competition with reductive elimination: improvement in the interpretation of the mechanism of biaryl syntheses.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Functional group tolerant Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles: catalysis by a nickel pincer complex permits the coupling of functionalized Grignard reagents.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Pd(PPh3)4-PEG 400 catalyzed protocol for the atom-efficient Stille cross-coupling reaction of organotin with aryl bromides.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Cross coupling reactions of chiral secondary organoboronic esters with retention of configuration

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Identification of a highly efficient alkylated pincer thioimido-palladium(II) complex as the active catalyst in Negishi coupling

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Acceleration of reductive elimination of [Ar-Pd-C(sp3)] by a phosphine/electron-deficient olefin ligand: a kinetic investigation

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Cross-coupling reaction of alkyl halides with grignard reagents catalyzed by Ni, Pd, or Cu complexes with pi-carbon ligand(s).

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Kinetic studies on the stability and reactivity of beta-amino alkylzinc iodides derived from amino acids

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

A nonsymmetric pincer-catalyzed Suzuki-Miyaura arylation of benzyl halides and other nonactivated unusual coupling partners.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Whole structure-activity relationships of the fat-accumulation inhibitor (-)-ternatin: recognition of the importance of each amino acid residue

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Iron-catalyzed cross-coupling reactions between a bicyclic alkenyl triflate and Grignard reagents

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Preparation, structure, and reactivity of nonstabilized organoiron compounds. Implications for iron-catalyzed cross coupling reactions

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

The promise and challenge of iron-catalyzed cross coupling.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Palladium-catalyzed oxidative carbonylation of alkyl and aryl indium reagents with CO under mild conditions

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Negishi cross-couplings of unsaturated halides bearing relatively acidic hydrogen atoms with organozinc reagents.

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3075866

Nickel complexes of a pincer NN2 ligand: multiple carbon-chloride activation of CH2Cl2 and CHCl3 leads to selective carbon-carbon bond formation

26 October 2018

1 reference

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Enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine: the key to an efficient and practical synthesis of a glucokinase activator

26 October 2018

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Efficient preparation of terminal conjugated dienes by coupling of dienol phosphates with grignard reagents under iron catalysis

26 October 2018

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Enantioselective alkyl-alkyl Suzuki cross-couplings of unactivated homobenzylic halides

26 October 2018

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Unprecedented negishi coupling at C-br in the presence of a stannyl group as a convenient approach to pyridinylstannanes and their application in liquid crystal synthesis

26 October 2018

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Asymmetric total synthesis of ent-sandaracopimaradiene, a biosynthetic intermediate of oryzalexins

26 October 2018

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Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing eta(3)-allyl ligand as catalysts.

26 October 2018

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Iron-catalyzed cross-coupling of imidoyl chlorides with Grignard reagents.

26 October 2018

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Indole diterpenoid synthetic studies. The total synthesis of (+)-nodulisporic acid F.

26 October 2018

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Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine

26 October 2018

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Synthesis of the multisubstituted halogenated olefins via cross-coupling of dihaloalkenes with alkylzinc bromides

26 October 2018

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Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

26 October 2018

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Catalytic enantioselective Negishi reactions of racemic secondary benzylic halides

26 October 2018

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Convergent total synthesis of gymnocin-A and evaluation of synthetic analogues.

26 October 2018

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Ni-catalyzed alkylative dimerization of vinyl grignard reagents using alkyl fluorides.

26 October 2018

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Nickel-catalyzed cross-coupling of neopentyl arenesulfonates with methyl and primary alkylmagnesium bromides

26 October 2018

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Nickel-catalyzed cross-coupling reaction of alkyl halides with organozinc and Grignard reagents with 1,3,8,10-tetraenes as additives.

26 October 2018

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An extremely active catalyst for the Negishi cross-coupling reaction

26 October 2018

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Catalytic cross-coupling of alkylzinc halides with alpha-chloroketones

26 October 2018

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Total synthesis of (+)-scyphostatin, a potent and specific inhibitor of neutral sphingomyelinase

26 October 2018

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Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

26 October 2018

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An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain.

26 October 2018

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Iron-catalyzed cross-coupling reactions. A scalable synthesis of the immunosuppressive agent FTY720.

26 October 2018

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A rationally designed universal catalyst for Suzuki-Miyaura coupling processes

26 October 2018

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Synthesis of aromatic bisabolene natural products via palladium-catalyzed cross-couplings of organozinc reagents.

26 October 2018

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Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes

26 October 2018

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Palladium-catalyzed negishi cross-coupling reactions of unactivated alkyl iodides, bromides, chlorides, and tosylates

26 October 2018

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A convergent total synthesis of hemibrevetoxin B.

26 October 2018

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Ni- or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents

26 October 2018

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Total synthesis of (+)-phomactin a using a B-alkyl Suzuki macrocyclization

26 October 2018

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Enantioselective total synthesis of borrelidin

26 October 2018

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A concise formal total synthesis of (+/-)-strychnine by using a transannular inverse-electron-demand Diels-Alder reaction of a [3](1,3)idolo[3](3,6)pyridazinophane

26 October 2018

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Synthesis of 2'-substituted 4-bromo-2,4'-bithiazoles by regioselective cross-coupling reactions

26 October 2018

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Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings

26 October 2018

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Convergent approach to pumiliotoxin alkaloids. Asymmetric total synthesis of (+)-pumiliotoxins A, B, and 225F.

26 October 2018

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Nickel-catalyzed cross-coupling reaction of grignard reagents with alkyl halides and tosylates: remarkable effect of 1,3-butadienes

26 October 2018

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Nickel-catalyzed cross-coupling between functionalized primary or secondary alkylzinc halides and primary alkyl halides

26 October 2018

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Atom-efficient metal-catalyzed cross-coupling reaction of indium organometallics with organic electrophiles

26 October 2018

1 reference

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Reductive elimination of aryl halides from palladium(II).

26 October 2018

1 reference

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Concise formation of 4-benzyl piperidines and related derivatives using a Suzuki protocol

26 October 2018

1 reference

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Cobalt-Catalyzed Cross-Coupling Reactions

26 October 2018

1 reference

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N-Heterocyclic Carbenes in Late Transition Metal Catalysis

9 December 2018

1 reference

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The First General Method for Stille Cross-Couplings of Aryl Chlorides

9 December 2018

1 reference

12 December 2020

Coordination Chemistry of Aluminum, Gallium, and Indium at Transition Metals

1 reference

12 December 2020

Towards Efficient and Wide-Scope Metal-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions

1 reference

12 December 2020

Phosphane-Free Palladium-Catalyzed Coupling Reactions: The Decisive Role of Pd Nanoparticles

1 reference

12 December 2020

Formation of organomagnesium compounds via EtMgBr-mediated radical cyclization of allyl beta-iodoacetals

1 reference

12 December 2020

Use of thallium(I) ethoxide in Suzuki cross coupling reactions

1 reference

12 December 2020

Transannular macrocyclization via intramolecular B-alkyl Suzuki reaction

1 reference

12 December 2020

Transition Metal Catalyzed Preparation of Grignard Compounds This work was supported by the Fonds der Chemische Industrie. We thank Prof. Dr. M. T. Reetz and Prof. Dr. P. Jolly for their support and numerous helpful discussions

1 reference

12 December 2020

Palladium-catalyzed cross-coupling reaction of organoindiums with aryl halides in aqueous media

1 reference

12 December 2020

Cross-coupling reactions of potassium alkyltrifluoroborates with aryl and 1-alkenyl trifluoromethanesulfonates

1 reference

12 December 2020

Room-temperature alkyl-alkyl Suzuki cross-coupling of alkyl bromides that possess beta hydrogens

1 reference

12 December 2020

Nickel-promoted alkylative or arylative carboxylation of alkynes

1 reference

12 December 2020

Direct Formation of Secondary and Tertiary Alkylzinc Bromides and Subsequent Cu(I)-Mediated Couplings

1 reference

12 December 2020

Nickel-Catalyzed Preparations of Functionalized Organozincs

1 reference

12 December 2020

Preparation of Functionalized Dialkylzincs via a Boron−Zinc Exchange. Reactivity and Catalytic Asymmetric Addition to Aldehydes

1 reference

12 December 2020

Nickel-Catalyzed Cross-Coupling of Dienyl Phosphates with Grignard Reagents in the Synthesis of 2-Substituted 1,3-Dienes

1 reference

12 December 2020

New Efficient Nickel-Catalyzed Cross-Coupling Reaction between Two Csp(3) Centers

1 reference

12 December 2020

Palladium-imidazolium carbene catalyzed aryl, vinyl, and alkyl Suzuki-Miyaura cross coupling

1 reference

12 December 2020

Nickel-catalyzed cross-couplings of 4-diethylphosphonooxycoumarins with organozinc reagents: an efficient new methodology for the synthesis of 4-substituted coumarins

1 reference

12 December 2020

Transition Metal-Catalyzed Activation of Aliphatic C−X Bonds in Carbon−Carbon Bond Formation

1 reference

12 December 2020

A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10)

1 reference

12 December 2020

Palladium(0)-catalyzed coupling of organozinc iodide reagents with bromopyridines: synthesis of selectively protected pyridine-containing azamacrocycles

1 reference

12 December 2020

Stereocontrolled total synthesis of (-)-ebelactone A

1 reference

12 December 2020

Suzuki cross-couplings of alkyl tosylates that possess beta hydrogen atoms: synthetic and mechanistic studies

1 reference

12 December 2020

Multifold and sequential cross-coupling reactions with indium organometallics

1 reference

12 December 2020

The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis A list of abbreviations can be found at the end of the article

1 reference

12 December 2020

Iron-Catalyzed Cross-Coupling Reactions

1 reference

12 December 2020

Preparation of new functionalized cyclopropylmagnesium reagents

1 reference

12 December 2020

A catalytic approach to (R)-(+)-muscopyridine with integrated "self-clearance"

1 reference

12 December 2020

Advances in functional-group-tolerant metal-catalyzed alkyl-alkyl cross-coupling reactions

1 reference

12 December 2020

Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2

1 reference

12 December 2020

B-Alkyl Suzuki−Miyaura Cross-Coupling Reactions with Air-Stable Potassium Alkyltrifluoroborates

1 reference

12 December 2020

Total synthesis and structural elucidation of (-)-delactonmycin

1 reference

12 December 2020

Orthopalladated and -platinated Bulky Triarylphosphite Complexes: Synthesis, Reactivity and Application as High-Activity Catalysts for Suzuki and Stille Coupling Reactions

1 reference

12 December 2020

Catalysis‐Based Total Synthesis of Latrunculin B

1 reference

12 December 2020

Cross-couplings of unactivated secondary alkyl halides: room-temperature nickel-catalyzed Negishi reactions of alkyl bromides and iodides

1 reference

12 December 2020

Tetraorganoindates as nucleophilic coupling partners in Pd-catalyzed cross-coupling reactions

1 reference

12 December 2020

Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides

1 reference

12 December 2020

Suzuki cross-couplings of unactivated secondary alkyl bromides and iodides

1 reference

12 December 2020

Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents

1 reference

12 December 2020

Selective iron-catalyzed cross-coupling reactions of grignard reagents with enol triflates, acid chlorides, and dichloroarenes

1 reference

12 December 2020

Total Synthesis of Natural (+)-(2‘S,3‘R)-Zoapatanol

1 reference

12 December 2020

Highly efficient Pd-catalyzed carbonylative cross-coupling reactions with tetraorganoindates

1 reference

12 December 2020

An active ferrocenyl triarylphosphine for palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl halides

1 reference

12 December 2020

Stille cross-coupling of activated alkyltin reagents under "ligandless" conditions

1 reference

12 December 2020

Asymmetric nickel-catalyzed Negishi cross-couplings of secondary alpha-bromo amides with organozinc reagents

1 reference

12 December 2020

Facile synthesis of multisubstituted buta-1,3-dienes via Suzuki-Miyaura and Kumada cross-coupling strategy of 2,4-diiodo-buta-1-enes with arylboronic acids and Grignard reagents

1 reference

12 December 2020

Heteroannulation of nitroketene N,S-arylaminoacetals with POCl3: a novel highly regioselective synthesis of unsymmetrical 2,3-substituted quinoxalines

1 reference

12 December 2020

Couplings with monoorganotin compounds: a "radical" twist from the original Stille reaction

1 reference

12 December 2020

Palladium-catalyzed coupling of thiol esters with aryl and primary and secondary alkyl organoindium reagents

1 reference

12 December 2020

Exploring new uses for C-H amination: Ni-catalyzed cross-coupling of cyclic sulfamates

1 reference

12 December 2020

Access to isocarbacyclin derivatives via substrate-controlled enolate formation: total synthesis of 15-deoxy-16-(m-tolyl)- 17,18,19,20-tetranorisocarbacyclin

1 reference

12 December 2020

Organosulfur compounds: electrophilic reagents in transition-metal-catalyzed carbon-carbon bond-forming reactions

1 reference

12 December 2020

Unusual structure and reactivity of a homoleptic "super-ate" complex of iron: implications for Grignard additions, cross-coupling reactions, and the Kharasch deconjugation

1 reference

12 December 2020

Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics

1 reference

12 December 2020

Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalyst

1 reference

12 December 2020

A room temperature negishi cross-coupling approach to C-alkyl glycosides

1 reference

12 December 2020

Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination

1 reference

12 December 2020

Suzuki-miyaura cross-coupling of 1,1-dichloro-1-alkenes with 9-alkyl-9-BBN

1 reference

12 December 2020

Oxidative addition reactions of alkyl halides with the group 13 carbene analogue [In{N(Dipp)C(Me)}2CH] (Dipp=2,6-iPr2C6H3)

1 reference

12 December 2020

Iron-catalyzed alkylations of aromatic grignard reagents

1 reference

12 December 2020

Total Synthesis of Amphidinolide Y by Formation of Trisubstituted (E)-Double Bond via Ring-Closing Metathesis of Densely Functionalized Alkenes§

1 reference

12 December 2020

One-pot amidation of olefins through Pd-catalyzed coupling of alkylboranes and carbamoyl chlorides

1 reference

12 December 2020

Easily accessible and highly tunable indolyl phosphine ligands for Suzuki-Miyaura coupling of aryl chlorides

1 reference

12 December 2020

Synthesis of the C3-C18 fragment of amphidinolides G and H

1 reference

12 December 2020

Investigations on the Suzuki-Miyaura and Negishi couplings with alkenyl phosphates: application to the synthesis of 1,1-disubstituted alkenes

1 reference

12 December 2020

Ni-catalyzed cascade formation of C(sp3)--C(sp3) bonds by cyclization and cross-coupling reactions of iodoalkanes with alkyl zinc halides

1 reference

12 December 2020

Superior effect of a pi-acceptor ligand (phosphine-electron-deficient olefin ligand) in the Negishi coupling involving alkylzinc reagents

1 reference

12 December 2020

Direct aminoalkylation of arenes and hetarenes via Ni-catalyzed Negishi cross-coupling reactions

1 reference

12 December 2020

Iron-catalyzed desulfinylative C-C cross-coupling reactions of sulfonyl chlorides with grignard reagents

1 reference

12 December 2020

Nickel-catalyzed asymmetric negishi cross-couplings of secondary allylic chlorides with alkylzincs

1 reference

12 December 2020

Suzuki-Miyaura cross-coupling of potassium trifluoroboratohomoenolates

1 reference

12 December 2020

Second-generation total synthesis of haterumalide NA using B-alkyl Suzuki-Miyaura coupling

1 reference

12 December 2020

Total synthesis of (+)-oocydin A: application of the Suzuki-Miyaura cross-coupling of 1,1-dichloro-1-alkenes with 9-alkyl 9-BBN

1 reference

12 December 2020

Effective Pd-Nanoparticle (PdNP)-Catalyzed Negishi Coupling Involving Alkylzinc Reagents at Room Temperature

1 reference

12 December 2020

Beyond Aresta's complex: Ni- and Pd-catalyzed organozinc coupling with CO2

1 reference

12 December 2020

Nickel-catalyzed carboxylation of organozinc reagents with CO2

1 reference

12 December 2020

Palladium-phosphinous acid-catalyzed cross-coupling of aryl and acyl halides with aryl-, alkyl-, and vinylzinc reagents

1 reference

12 December 2020

Palladium- and nickel-catalyzed cross-couplings of unsaturated halides bearing relatively acidic protons with organozinc reagents

1 reference

12 December 2020

Nickel-Catalyzed Cross-Coupling of Non-activated and Functionalized Alkyl Halides with Alkyl Grignard Reagents

1 reference

12 December 2020

High ortho preference in Ni-catalyzed cross-coupling of halophenols with alkyl grignard reagents

1 reference

12 December 2020

Synthesis of 3,4-disubstituted maleimides by selective cross-coupling reactions using indium organometallics

1 reference

12 December 2020

Nickel Complexes of a Pincer Amidobis(amine) Ligand: Synthesis, Structure, and Activity in Stoichiometric and Catalytic CC Bond-Forming Reactions of Alkyl Halides

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12 December 2020

Nickel-catalyzed synthesis of oxazoles via C-S activation

1 reference

12 December 2020

Total synthesis of jatrophane diterpenes from Euphorbia characias

1 reference

12 December 2020

Mild room-temperature palladium-catalyzed C3-arylation of 2(1H)-pyrazinones via a desulfitative Kumada-type cross-coupling reaction

1 reference

12 December 2020

Pd-catalyzed cross-coupling of functionalized organozinc reagents with thiomethyl-substituted heterocycles

1 reference

12 December 2020

Method for palladium-catalyzed cross-couplings of simple alkyl chlorides: Suzuki reactions catalyzed by [Pd2(dba)3]/PCy3

1 reference

12 December 2020

Heteroaromatic sulfonates and phosphates as electrophiles in iron-catalyzed cross-couplings

1 reference

12 December 2020

Nickel-catalyzed cross-coupling of alkyl zinc halides for the formation of C(sp(2))-C(sp(3)) bonds: scope and mechanism

1 reference

12 December 2020

Total synthesis of spirastrellolide F methyl ester--part 1: Strategic considerations and revised approach to the southern hemisphere

1 reference

12 December 2020

Total synthesis of spirastrellolide F methyl ester--part 2: Macrocyclization and completion of the synthesis

1 reference

12 December 2020

Room temperature cross-coupling of highly functionalized organozinc reagents with thiomethylated N-heterocycles by nickel catalysis

1 reference

12 December 2020

Palladium-catalyzed aerobic oxidative cross-coupling reactions of terminal alkynes with alkylzinc reagents

1 reference

12 December 2020

The Nickel/Copper-Catalyzed Direct Alkylation of Heterocyclic CH Bonds

1 reference

12 December 2020

Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)

1 reference

12 December 2020

Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl

1 reference

12 December 2020

Cross-coupling reactions through the intramolecular activation of alkyl(triorgano)silanes

1 reference

12 December 2020

i-PrI acceleration of Negishi cross-coupling reactions

1 reference

12 December 2020

On the role of additives in alkyl-alkyl Negishi cross-couplings

1 reference

12 December 2020

Highly diastereoselective Csp3–Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds

1 reference

12 December 2020

An Efficient Nickel-Catalyzed Cross-Coupling Between sp3 Carbon Centers

1 reference

12 December 2020

Efficient Suzuki-Type Cross-Coupling of Enantiomerically Pure Cyclopropylboronic Acids

1 reference

12 December 2020

Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones

1 reference

19 October 2022

https://opencitations.net/index/coci/api/v1/citations/10.1016/0040-4039(91)80445-C

Palladium-catalyzed inter- and intramolecular cross-coupling reactions of B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with 1-halo-1-alkenes or haloarenes. Syntheses of functionalized alkenes, arenes, and cycloalkenes via a hydroboration-coupling

1 reference

19 October 2022

https://opencitations.net/index/coci/api/v1/citations/10.1021/JA00183A048

Identifiers

DOI

10.1021/CR100327P

1 reference

4 August 2017

1 reference

4 August 2017

1 reference